26581-23-7

Basic information

• Product Name: Benzoic acid, 4-(1-methylethenyl)-, methyl ester
• Synonyms: methyl 4-(prop-1-en-2-yl)benzoate;4-Isopropenyl-benzoesaeure-methylester;methyl 4-isopropenylbenzoate;4-isopropenyl-benzoic acid methyl ester
• CAS NO: 26581-23-7
• Molecular Formula: C11H12O2
• Molecular Weight: 176.215
• Mol File: 26581-23-7.mol
• Article Data: 16

Chemical Properties

• CAS DataBase Reference: Benzoic acid, 4-(1-methylethenyl)-, methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: Benzoic acid, 4-(1-methylethenyl)-, methyl ester(26581-23-7)
• EPA Substance Registry System: Benzoic acid, 4-(1-methylethenyl)-, methyl ester(26581-23-7)

Safety Data

• Hazardous Substances Data: 26581-23-7(Hazardous Substances Data)

Upstream product

• 187737-37-7 propene 
• 20883-45-8 4-methoxycarbonyl-phenylmercury ⁽¹⁺⁾; chloride 
• 7647-01-0 hydrogenchloride 
• 67-56-1 methanol 
• 3609-50-5 4-(2-hydroxypropan-2-yl)benzoic acid 
• 74-88-4 methyl iodide 
• 108-22-5 Isopropenyl acetate 
• 1126-46-1 Methyl 4-chlorobenzoate 
• 619-42-1 4-methoxycarbonylphenyl bromide 
• 18107-18-1 diazomethyl-trimethyl-silane 
• 1132773-51-3 2,4-di-p-carboxyphenyl-2,4-dimethyl-3-pentanone dimethyl ester 
• 1830-69-9 4-(prop-1-en-2-yl)benzoic acid 
• 75-24-1 trimethylaluminum 
• 7377-26-6 4-Methoxycarbonylbenzoyl chloride 

Downstream Products

• 1227210-77-6 C₁₁H₁₄O₄ 
• 131170-40-6 2-methyl-4-(1-methylcyclopropyl)benzoic acid 
• 1622303-33-6 N-(3-bromo-2-(((tert-butyldimethylsilyl)oxy)methyl)phenyl)-4-(1-methylcyclopropyl)benzamide 
• 1622303-32-5 methyl 4-(1-methylcyclopropyl)benzoate 
• 10133-50-3 4-formyl-α-methylstyrene 
• 75-89-8 2,2,2-trifluoroethanol 
• 75-90-1 2,2,2-Trifluoroacetaldehyde 
• 3609-53-8 methyl 4-acetylbenzoate 
• 240407-05-0 C₁₂H₁₄O₃ 
• 129488-73-9 methyl 4-(1-cyano-1-methylethyl)-benzoate 

Relevant articles and documents

Electrochemical fluorosulfonylation of alkenes to access vicinal fluorinated sulfones derivatives

Herein, we report a practical and efficient fluorosulfonylation of the various alkenes with sulfonyl radical sources (RSO2NHNH2) and Et3N·3HF as cost-effective fluorination reagents under mild conditions. Remarkably, this

Palladium/Acid Relay Catalyzed Tandem Heck Coupling/6-Endo Cyclization between ortho-Halogenated Benzoates and Unactivated Terminal Alkenes for the Synthesis of 1-Isochromanones

We report a unique and expeditious route to synthesize 1-isochromanone derivatives through palladium catalyzed tandem Heck coupling/6-endo hydroacyloxylation cyclization between readily available ortho-halogenated benzoates and unactivated alkenes. Various 2-bromo or 2-iodo benzoates can be coupled efficiently with a broad range of alkenes to afford functionalized 1-isochromanones in high yields. Significantly, this cost-efficient and easy-to-handle synthetic methodology will have great prospect application in the synthetic and medicinal chemistry. (Figure presented.).

Synthesis of 2-Substituted Propenes by Bidentate Phosphine-Assisted Methylenation of Acyl Fluorides and Acyl Chlorides with AlMe3

Bidentate phosphine-assisted methylenation of acyl fluorides and acyl chlorides with substituted with aryl, alkenyl, and alkyl groups trimethylaluminum afforded an array of 2-substituted propene derivatives. The addition of a catalytic amount of DPPM increased an efficiency of the reactions. Trimethylaluminum as the methylenation reagent not only eliminates the presynthesis of methylene transfer reagent, but provides an efficient method for the synthesis of a series of 2-substituted propenes.