26672-60-6

Basic information

• Product Name: 1-Butanone, 1-[4-(dimethylamino)phenyl]-
• CAS NO: 26672-60-6
• Molecular Formula: C12H17NO
• Molecular Weight: 191.273
• Mol File: 26672-60-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-Butanone, 1-[4-(dimethylamino)phenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Butanone, 1-[4-(dimethylamino)phenyl]-(26672-60-6)
• EPA Substance Registry System: 1-Butanone, 1-[4-(dimethylamino)phenyl]-(26672-60-6)

Safety Data

• Hazardous Substances Data: 26672-60-6(Hazardous Substances Data)

Upstream product

• 121-69-7 N,N-dimethyl-aniline 
• 141-75-3 butyryl chloride 
• 107-92-6 butyric acid 
• 557-93-7 2-bromoprop-1-ene 
• 100-10-7 4-dimethylamino-benzaldehyde 

Downstream Products

• 1426669-67-1 4-(1-(benzylimino)butyl)-N,N-dimethylaniline 
• 1426669-71-7 C₂₆H₃₀N₂O₄ 
• 1426669-73-9 1-benzyl-6-(4-(dimethylamino)phenyl)-5-ethyl-4-methoxy-2-oxo-1,2-dihydropyridine-3-carboxylic acid 
• 1426669-69-3 ethyl 1-benzyl-6-(4-(dimethylamino)phenyl)-5-ethyl-4-hydroxy-2-oxo-1,2-dihydropyridine-3-carboxylate 
• 1426668-59-8 6-[4-(dimethylamino)phenyl]-5-ethyl-4-methoxy-2-oxo-1,2-dihydropyridine-3-carboxylic acid 
• 13330-29-5 4-n-butyl-N,N-dimethylaniline 
• 861532-71-0 1-(4-dimethylamino-phenyl)-butan-1-ol 
• 101275-52-9 4-[4-(4-dimethylamino-phenyl)-4-oxo-butyryl]-morpholine 

Relevant articles and documents

Conversion of Aldehydes to Branched or Linear Ketones via Regiodivergent Rhodium-Catalyzed Vinyl Bromide Reductive Coupling-Redox Isomerization Mediated by Formate

A regiodivergent catalytic method for direct conversion of aldehydes to branched or linear alkyl ketones is described. Rhodium complexes modified by PtBu2Me catalyze formate-mediated aldehyde-vinyl bromide reductive coupling-redox isomerization to form branched ketones. Use of the less strongly coordinating ligand, PPh3, promotes vinyl-to allylrhodium isomerization en route to linear ketones. This method bypasses the 3-step sequence often used to convert aldehydes to ketones involving the addition of pre-metalated reagents to Weinreb or morpholine amides.