26728-45-0Relevant academic research and scientific papers
Rhodium-catalyzed asymmetric synthesis of β-branched esters from allylic amines
Laffoon, Summer D.,Wu, Zhao,Hull, Kami L.
supporting information, p. 7814 - 7817 (2018/07/25)
Allylic amines are converted to chiral, β-branched esters under rhodium catalysis in the presence of alcohol nucleophiles. Allylic amines with aliphatic and aromatic vinylic substituents are converted to ester products with excellent enantioselectivities in all cases. Several alcohol nucleophiles have been utilized in the reaction including 1° and 2° derivatives.
Nickel-catalyzed dehydrogenative cross-coupling: Direct transformation of aldehydes into esters and amides
Whittaker, Aaron M.,Dong, Vy M.
supporting information, p. 1312 - 1315 (2015/01/30)
By exploring a new mode of nickel-catalyzed cross-coupling, a method to directly transform both aromatic and aliphatic aldehydes into either esters or amides has been developed. The success of this oxidative coupling depends on the appropriate choice of catalyst and organic oxidant, including the use of either α,α,α-trifluoroacetophenone or excess aldehyde. Mechanistic data that supports a catalytic cycle involving oxidative addition into the aldehyde C-H bond is also presented.
OZONOLYSIS OF ALKENES AND THE REACTIONS OF POLYFUNCTIONAL COMPOUNDS LIII.SYNTHESIS OF THE ESTERS OF 2,3-DIHYDRO DERIVATIVES OF TRI-, DI-, AND MONOPRENOIC ACIDS
Odinokov, V. N.,Kukovinets, O. S.,Sakharova, N. I.,Tolstikov, G. A.
, p. 24 - 30 (2007/10/02)
The esters of the 2,3-dihydro derivatives of geranylgeranic, farnesylic, and geranic acids (di-, sesqui-, and monoterpenoid acids) were synthesized from the products from ozonolysis of 1,5,9-trimethyl-1E,5E,9E-cyclododecatriene.
