40267-53-6

Basic information

• Product Name: (E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine
• Synonyms: (2E)-N,N-Diethyl-3,7-dimethyl-2,6-octadien-1-amine;(E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine
• CAS NO: 40267-53-6
• Molecular Formula: C₁₄H₂₇N
• Molecular Weight: 209.3709
• Mol File: 40267-53-6.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 277.6°Cat760mmHg
• Flash Point: 111.3°C
• Appearance: /
• Density: 0.825g/cm³
• Vapor Pressure: 0.00447mmHg at 25°C
• Refractive Index: 1.467
• CAS DataBase Reference: (E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine(40267-53-6)
• EPA Substance Registry System: (E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine(40267-53-6)

Safety Data

• Hazardous Substances Data: 40267-53-6(Hazardous Substances Data)

Usage

General Description

(E)-N,N-Diethyl-3,7-dimethyl-2,6-octadiene-1-amine, also known as octodiene, is a chemical compound with the molecular formula C14H29N. It is a tertiary amine that is commonly used as a fragrance ingredient in perfumes and colognes. It has a floral, fruity, and slightly green odor and is often added to cosmetic and personal care products for its pleasant scent. Octodiene is also used as a flavoring agent in food products and as a chemical intermediate in the synthesis of other compounds. It is a clear, colorless liquid that is soluble in alcohol and oils, making it versatile for use in a variety of applications. However, it should be handled with care as it may cause skin and eye irritation.

InChI:InChI=1/C14H27N/c1-6-15(7-2)12-11-14(5)10-8-9-13(3)4/h9,11H,6-8,10,12H2,1-5H3/b14-11+

Upstream product

• 78-70-6 3,7-dimethylocta-1,6-dien-3-ol 
• 106-25-2 Nerol 
• 106-24-1 Geraniol 
• 6138-90-5 trans-geranyl bromide 
• 109-89-7 diethylamine 
• 123-35-3 7-methyl-3-methene-1,6-octadiene 
• 76027-22-0 N,N-diethyl-(E)-3,7-dimethyl-2,7-octadienylamine 
• 78-79-5 isoprene 
• 67-56-1 methanol 
• 870-63-3 prenyl bromide 
• 124-40-3 dimethyl amine 
• 5389-87-7 1-chloro-3,7-dimethylocta-2,6-diene 

Downstream Products

• 76192-32-0 C₁₄H₂₇NO 
• 5773-37-5 4,4-dimethyl-1-cyclohexene acetate 
• 26728-45-0 isopropyl (S)-3,7-dimethyloct-6-enoate 
• 26728-82-5 cyclohexyl (S)-3,7-dimethyloct-6-enoate 
• 73991-97-6 benzyl (S)-3,7-dimethyloct-6-enoate 
• 41034-88-2 N,N-diethyl-3,7-dimethyloct-6-en-1-amine 
• 98652-75-6 n-hexyl 3,7-dimethyl-6-octenoate 
• 5392-40-5 (E/Z)-3,7-dimethyl-2,6-octadienal 
• 31906-04-4 4-(4-hydroxy-4-methylpentyl)cyclohex-3-enecarbaldehyde 
• 543-39-5 myrcenol 
• 146918-65-2 Toluene-4-sulfonic acid 2,5,5-trimethyl-1,2,3,4,5,6,7,8-octahydro-naphthalen-2-ylmethyl ester 
• 19894-79-2 diethyl [(2E)-3,7-dimethylocta-2,6-dienyl]malonate 
• 2385-77-5 (R)-Citronellal 
• 5949-05-3 (S)-Citronellal 

Relevant articles and documents

Rhodium-Catalyzed Asymmetric Synthesis of β-Branched Amides

A general asymmetric route for the one-step synthesis of chiral β-branched amides is reported through the highly enantioselective isomerization of allylamines, followed by enamine exchange, and subsequent oxidation. The enamine exchange allows for a rapid and modular synthesis of various amides, including challenging β-diaryl and β-cyclic.

Copper(II) catalyzed allylic amination of terpenic chlorides in water

A highly efficient method for the synthesis of allylic amines from terpenic chlorides by cheap copper (II) as catalyst in water has been developed. Allylic chlorides react with high regioselectivity in the presence of secondary amines, under mild conditions to give N-allylic amines in excellent yields.

Process for producing optically active 3, 7-dimethyl-6-octenol and process for producing intermediate therefor

Provided is citronellol, which has an elegant rosy fragrance and is extremely useful for fragrance impartation to aromatic articles. A mixture of an alkylamine and isoprene in a molar ratio of from 1:4 to 1:4.5 is subjected to telomerization at 80 to 100° C. for 2.5 to 3.5 hours in the presence of an alkyllithium catalyst and/or phenyllithium catalyst to obtain a nerylamine compound containing 2 to 10 wt % α-nerylamine compound represented by general formula (4). From this nerylamine compound, citronellol containing 2 to 10 wt % optically active 3,7-dimethyl-7-octenol is produced through the reaction steps of asymmetric isomerization, hydrolysis, and hydrogenation.