26823-05-2Relevant academic research and scientific papers
RELATIVE KINETICS OF THE HOMOLYTIC ADDITION OF 2-PHENYL-1,3-DIOXOLANE TO UNSATURATED COMPOUNDS
Ryabinina, T. A.,Kruglov, D. E.,Pastushenko, E. V.,Terent'ev, A. B.
, p. 1289 - 1292 (1992)
The CH2=CHX olefins form a series relative to their reactivity in reactions with 2-phenyl-1,3-dioxolan-2-yl radicals, which qualitatively correlates with the electron-withdrawing capacity of substituent X: CN = ca.CO2Me >> SiMe3 = ca.C4H9.This behavior indicates that the dioxolanyl radical is nucleophilic.Keywords: radicals, addition, dioxolane, polar effect, kinetics.
RELATIVE REACTIVITY OF 2-PHENYL-1,3-DIOXOLAN IN THE RADICAL REACTION WITH UNSATURATED COMPOUNDS
Ryabinina, T. A.,Kruglov, D. E.,Pastushenko, E. V.,Terent'ev, A. B.
, p. 2320 - 2324 (2007/10/02)
The relative reactivities of 2-phenyl-1,3-dioxolan-2-yl radicals in reactions with α-olefins of different natures are determined.It is shown that 2-phenyl-1,3-dioxolan-2-yl radicals appear in addition reactions of homolytic weak nucleophilic properties.
