Bull. Russ. Acad. Sci. Div. Chem. Sci. (Engl. Transl.) p. 1289 - 1292 (1992)
Update date:2022-08-04
Topics:
Ryabinina, T. A.
Kruglov, D. E.
Pastushenko, E. V.
Terent'ev, A. B.
The CH2=CHX olefins form a series relative to their reactivity in reactions with 2-phenyl-1,3-dioxolan-2-yl radicals, which qualitatively correlates with the electron-withdrawing capacity of substituent X: CN = ca.CO2Me >> SiMe3 = ca.C4H9.This behavior indicates that the dioxolanyl radical is nucleophilic.Keywords: radicals, addition, dioxolane, polar effect, kinetics.
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