2696-79-9

Upstream product

• 505-14-6 thiocyanogen 
• 110-83-8 cyclohexene 
• 333-20-0 potassium thioacyanate 
• 96302-40-8 r-1-iodo-c-2-methoxy-t-6-thiocyanatocyclohexane 
• 1521-51-3 rac-3-bromocyclohexene 
• 2699-13-0 3-methoxycyclohexene 
• 87656-40-4 trans-1-isothiocyanato-2-(phenylseleno)cyclohexane 

Downstream Products

• 2696-80-2 cyclohex-2-enylthiourea 
• 51992-63-3 4-cyclohex-2-enyl-1-phenylacetyl-thiosemicarbazide 
• 2696-81-3 1-cyclohex-2-enyl-3-phenyl-thiourea 
• 1541-25-9 3-amino-1-cyclohexene 
• 88281-71-4 N-(2-Cyclohexenyl)-O-ethyl-thiocarbamat 

Relevant academic research and scientific papers

N-(4-Methoxyphenyl)-substituted bicyclic isothioureas: effect on morphology of cancer cells

Bicyclic isothioureas of N-(4-methoxyphenyl)-2-aminocycloalkane[d]thiazole type were obtained using intramolecular electrophilic cyclization of N-(cycloalk-2-enyl)-N′-(4-methoxyphenyl)thioureas. Isothiourea fused with sevenmembered ring caused noticeable

ALKYL AND ARYL ISOTHIOCYANATES AS MASKED PRIMARY AMINES

Primary and secondary (but not tertiary) alkyl as well as aryl isothiocyanates react rapidly with 4-methyl-1,2-benzenedithiol (1) in methanol at room temperature, releasing the corresponding amines in good yields.This mild and simple procedure for unmasking amines proceeds chemospecifically with isothiocyanates even in the presence of such normally electrophilic and reactive functionalities as carboxylate ester and N-alkylphthalimide.

vic-Iodothiocyanates and Iodoisothiocyanates. Part 8. Addition of Iodine-Thiocyanogen to Alkenes under Ionic and Radical Conditions

Addition of iodine-thiocyanogen to alkenes in the dark proceeds by a regioselective ionic reaction to give mainly vic-iodoisothiocyanates, and under irradiation with u.v. light by a radical reaction to give mainly vic-iodothiocyanates.However, in the case of 1-methylene-4-t-butylcyclohexane even under irradiation by u.v. light, ionic addition of the reagent competes successfully with, and almost to the exclusion of, the radical pathway.

Reaction of Olefins with a Mixture of Phenylselenenyl Chloride and Mercury(II) Thiocyanate. Selective Syntheses of β-(Phenylseleno)alkyl Isothiocyanates as Precursors of Vinylic Isothiocyanates

The reaction of olefins with a mixture of phenylselenenyl chloride and mercury(II) thiocyanate in benzene as the solvent affords β-(phenylseleno)alkyl isothiocyanates selectively in good to excellent yields.The mercury salt not only increases the N selectivity in a kinetically controlled reaction but also accelerates the isomerization of β-(phenylseleno)alkyl thiocyanates to the corresponding isothiocyanates.Oxidative elimination of the β-(phenylseleno)alkyl isothiocyanates gives predominantly vinylic isothiocyanates together with a small amount of allylic isothiocyanate s.This sequence constitutes a convenient method for conversion of olefins to vinylic isothiocyanates.