2699-12-9Relevant articles and documents
Six Peroxide Groups in One Molecule - Synthesis of Nine-Membered Bicyclic Silyl Peroxides
Arzumanyan, Ashot V.,Terent'ev, Alexander O.,Novikov, Roman A.,Lakhtin, Valentin G.,Chernyshev, Vladimir V.,Fitch, Andrew N.,Nikishin, Gennady I.
, p. 6877 - 6883 (2014)
Comounds containing two nine-membered peroxide rings bridged by an ethane, ethene, or ethyne group were synthesized by the reactions of 1,2-bis[dichloro(alkyl)silyl]ethanes, (E)-1,2-bis[dichloro(methyl)silyl]ethene, or 1,2-bis[dichloro(methyl)silyl]ethyne
Similar nature leads to improved properties: Cyclic organosilicon triperoxides as promising curing agents for liquid polysiloxanes
Deriabin, Konstantin V.,Yaremenko, Ivan A.,Chislov, Mikhail V.,Fleury, Fabrice,Terent'Ev, Alexander O.,Islamova, Regina M.
, p. 15006 - 15013 (2018/09/29)
Cyclic organosilicon triperoxides were found to be vinyl-selective free-radical initiators for thermal curing at 100-180 °C of vinyl-terminated polydimethylsiloxane and trimethylsilyl-terminated polymethylhydrosiloxane producing homogeneous transparent si
Cyclohexane oxidation: Small organic molecules as catalysts
Zhang, Yicheng,Dai, Weili,Wu, Guangjun,Guan, Naijia,Li, Landong
, p. 279 - 285 (2014/04/03)
The catalytic activity of several small organic molecules including ketones, aldehydes, esters, alcohols and amines toward cyclohexane oxidation was investigated. The catalytic activity was found to be closely related to polarity, α-H activity, the strength of hydrogen bond formed with cyclohexane and the radical scavenging capability of these molecules. Based on the obtained results, the catalytic role of the organic solvent must be considered for cyclohexane oxidation. Tripropylamine has very high activity in cyclohexane oxidation and it might be further developed as a promising small-molecule organocatalyst for future application.
