27008-35-1

Upstream product

• 5920-84-3 2-bromo-4,6-di-tert-butylphenyl trimethylsilyl ether 
• 20834-61-1 2-bromo-4,6-di-tert-butylphenol 

Downstream Products

• 1334501-74-4 N-(2-(3-(tert-butyl)-5-(trimethylsilyl)phenyl)-2-methylpropyl)aniline 
• 97391-27-0 2,4-di-tert-butyl-6-(trimethylsilyl)phenyl trifluoromethanesulfonate 
• 5920-86-5 4.6-Di-tert.-butyl-2-trimethylsilylphenoxyradikal 
• 53925-65-8 (2,4-di-tert-butylphenoxy)trimethylsilane 
• 16339-84-7 2,2'-Bis-trimethylsiloxy-3,3',5,5'-tetra-tert-butyl-diphenyl 

Relevant academic research and scientific papers

Palladium(0)-catalyzed intermolecular amination of unactivated Csp 3-H bonds

Filling out the space: The title reaction of unactivated Csp3-H bonds using aryl amines as the nitrogen source is disclosed (see scheme; dba=dibenzylideneacetone, Tf=trifluoromethanesulfonyl). Either the C-N cross-coupling product or the C-H am

Mechanism of dimerization-rearrangement of organosilicon aroxyls

Organosilicon aroxyls form disiloxyhiaryls via C-C dimerization with simultaneous (or subsequent) isomerization of the dimeric intermediate, involving migration of the ortho-organosilyl substituents from carbon to oxygen.