5920-84-3Relevant academic research and scientific papers
Microflow fluorinations of benzynes: Efficient synthesis of fluoroaromatic compounds
Ikawa, Takashi,Masuda, Shigeaki,Akai, Shuji
, p. 1153 - 1164 (2018/12/10)
Fluorinated aromatic compounds are found in a variety of biologically active compounds, including clinical drugs and agrochemicals. Therefore, the synthesis of aryl fluorides is particularly important in the medicinal and process chemistry fields. In this
Multiple intra-molecular hydrogen bonds in 2,4-di-tert-butyl-6-[N-(2,6- diisopropylphenyl)-P,P-diphenylphosphorimidoyl]phenol
Lee, Jong-Dae,Suh, Il-Hwan,Kang, Sang Ook
scheme or table, p. o151-o153 (2011/06/26)
The title compound, C38H48NOP, isolated from the reaction of (2-diphenyl-phosphanyl-4,6-di-tert-butyl)phenol with 2,6-di-iso-propyl-phenyl -azide at 273 K, can act as an N,O-bidentate ligand. Crystal structure analysis shows a deviat
Palladium(0)-catalyzed intermolecular amination of unactivated Csp 3-H bonds
Pan, Jun,Su, Mingjuan,Buchwald, Stephen L.
supporting information; experimental part, p. 8647 - 8651 (2011/11/06)
Filling out the space: The title reaction of unactivated Csp3-H bonds using aryl amines as the nitrogen source is disclosed (see scheme; dba=dibenzylideneacetone, Tf=trifluoromethanesulfonyl). Either the C-N cross-coupling product or the C-H am
Synthesis of aryl stannanes from silyl triflates via aryne intermediates
Lakshmi, B. Vasantha,Wefelscheid, Ulrike K.,Kazmaier, Uli
supporting information; experimental part, p. 345 - 348 (2011/04/15)
Aryl stannanes are easily accessible from o-silylated aryl triflates in the presence of KF and Bu3SnH. The corresponding arynes are formed in situ, and undergo clean hydrostannation to give a mixture of the regioisomeric aryl stannanes. The whole reaction sequence can also be carried out as a one-pot reaction under microwave irradiation. Georg Thieme Verlag Stuttgart New York.
