2717-67-1

Basic information

• Product Name: Diazene, dimethyl-, 1,2-dioxide
• CAS NO: 2717-67-1
• Molecular Formula: C2H6N2O2
• Molecular Weight: 90.0818
• Mol File: 2717-67-1.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Diazene, dimethyl-, 1,2-dioxide(CAS DataBase Reference)
• NIST Chemistry Reference: Diazene, dimethyl-, 1,2-dioxide(2717-67-1)
• EPA Substance Registry System: Diazene, dimethyl-, 1,2-dioxide(2717-67-1)

Safety Data

• Hazardous Substances Data: 2717-67-1(Hazardous Substances Data)

Upstream product

• 75-52-5 nitromethane 
• 67-63-0 isopropyl alcohol 
• 680-31-9 N,N,N,N,N,N-hexamethylphosphoric triamide 
• 937-14-4 3-chloro-benzenecarboperoxoic acid 
• 85437-82-7 ((bis(dimethylamino)phosphinyl)oxy)dimethylamine 
• 85437-83-8 C₆H₁₆NO₄P 
• 2404-03-7 diethyl N,N-dimethylphosphoramide 
• 924-43-6 sec-butyl nitrite 
• 110-22-5 diacetyl peroxide 
• 66809-88-9 N-methyl-O-benzoylhydroxylamine 

Downstream Products

• 75-17-2 formaldoxime 
• 87406-53-9 -azoxybis(methylene) bis(3-chlorobenzoate) 

Relevant articles and documents

Copper-Catalyzed Redox Deacylation of Isomeric N- and O-Benzoylhydroxylamines

N- and O-benzoylhydroxylamines are, in principle, capable of forming five-membered metal chelates structurally similar to those of α-amino esters.Because α-amino esters are hydrolyzed by many metal ions, the metal-promoted or -catalyzed reactions of N- and O-benzoylhydroxylamines were examined.Two metals that are active with α-amino esters - Ni(II) and Zn(II) - show no reaction with either benzohydroxamic acid or O-benzoylhydroxylamine in aqueous solution.Cu(II) accelerates the rate of benzoic acid formation with both compounds by factors of up to 60- and 40-fold, respectively, under the conditions evaluated.Both reactions give benzoic acid as product, but hydroxylamine is not a product in either reaction.We observe that O-benzoylhydroxylamine reacts with Cu(II) with net oxidation and with Cu(I) with net reduction of the nitrogenous product.When a substoichiometric amount of Cu(II) is used, copper serves as a catalyst to effect deacylation with redox disproportionation of the starting material.

Peracid-mediated N-oxidation and rearrangement of dimethylphosphoramides: Plausible model for oxidative bioactivation of the carcinogen hexamethylphosphoramide (HMPA)

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