2724-57-4

Basic information

• Product Name: 12-METHYLTRIDECANOIC ACID
• Synonyms: 12-METHYLTRIDECANOIC ACID;ISOMYRISTIC ACID;Tridecanoic acid, 12-methyl;aseanostatin P1
• CAS NO: 2724-57-4
• Molecular Formula: C₁₄H₂₈O₂
• Molecular Weight: 228.37
• Mol File: 2724-57-4.mol
• Article Data: 5

Chemical Properties

• Melting Point: 53.3-53.6 °C
• Boiling Point: 320.89°C (estimate)
• Flash Point: 187.2°C
• Appearance: /
• Density: 0.8577 (rough estimate)
• Vapor Pressure: 1.68E-05mmHg at 25°C
• Refractive Index: 1.4312 (estimate)
• Storage Temp.: 2-8°C
• PKA: 4.78±0.10(Predicted)
• CAS DataBase Reference: 12-METHYLTRIDECANOIC ACID(CAS DataBase Reference)
• NIST Chemistry Reference: 12-METHYLTRIDECANOIC ACID(2724-57-4)
• EPA Substance Registry System: 12-METHYLTRIDECANOIC ACID(2724-57-4)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26-36
• WGK Germany: 3
• Hazardous Substances Data: 2724-57-4(Hazardous Substances Data)

Usage

Uses

12-Methyltridecanoic Acid is a branched fatty acid found naturally in fish and in other Asian fermented foods.

InChI:InChI=1/C14H28O2/c1-13(2)11-9-7-5-3-4-6-8-10-12-14(15)16/h13H,3-12H2,1-2H3,(H,15,16)

Upstream product

• 857078-90-1 12-methyl-tridec-7-ynoic acid 
• 83855-20-3 Neopeptin A 
• 112-80-1 cis-Octadecenoic acid 
• 112-38-9 10-undecenoic acid 
• 626-89-1 4-Methyl-1-pentanol 
• 1119-16-0 isocaproic aldehyde 
• 111-81-9 Methyl 10-undecenoate 
• 85763-57-1 11-methyl-1-dodecanol 
• 106787-53-5 11-methyl-dodec-1-ene 
• 34386-60-2 11-hydroxy-11-methyl-dodec-1-ene 
• 856940-20-0 6-(5-isobutyl-thiophen-2-yl)-6-oxo-hexanoic acid 
• 70794-53-5 <1-(ethoxycarbonyl)decyl>triphenylphosphonium iodide 
• 93190-73-9 2-Methyl-tridecen-⁽²⁾-saeure-⁽¹³⁾-ethylester 
• 4548-78-1 (3-methylbutyl)magnesium bromide 

Downstream Products

• 1603-03-8 isomargaric acid 
• 2724-58-5 16-methylheptadecanoic acid 
• 2485-71-4 13-methyltetradecanoic acid 
• 5129-58-8 methyl 12-methyltridecanoate 
• 103279-01-2 2-(19-methyl-eicosyl)-1H-benzimidazole 
• 75853-49-5 12-methyltridecan-1-al 
• 92168-98-4 11-methyldodecanal 

Relevant articles and documents

A practical synthesis of long-chain iso-fatty acids (iso-C 12-C19) and related natural products

A gram-scale synthesis of terminally-branched iso-fatty acids (iso-C 12-C19) was developed commencing with methyl undec-10-enoate (methyl undecylenate) (for iso-C12-C14) or the C15 and C16 lactones pentadecanolide (for iso-C 15-C17) and hexadecanolide (for iso-C18-C 19). Central to the approaches outlined is the two-step construction of the terminal isopropyl group through addition of methylmagnesium bromide to the ester/lactones and selective reduction of the resulting tertiary alcohols. Thus, the C12, C17 and C18 iso-fatty acids were obtained in three steps from commercially-available starting materials, and the remaining C13-C16 and C19 iso-fatty acids were prepared by homologation or recursive dehomologations of these fatty acids or through intercepting appropriate intermediates. Highlighting the synthetic potential of the iso-fatty acids and various intermediates prepared herein, we describe the synthesis of the natural products (S)-2,15-dimethylpalmitic acid, (S)-2-hydroxy-15-methylpalmitic acid, and 2-oxo-14-methylpentadecane.

Synthesis and Absolute Configuration of 2-Hydroxy-12-methyl Tridecanoic Acid

The synthesis of racemic 2-hydroxy-12-methyl tridecanoic acid is described.The absolute configuration of the two enantiomers has been determined by the method of Dale and Mosher. - Keywords: 2-Hydroxy-12-methyl Tridecanoic Acid, Absolute COnfiguration

Structure and biological activity of neopeptins A, B and C, inhibitors of fungal cell wall glycan synthesis

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