27389-56-6

Basic information

• Product Name: N,N,N-trimethyl-4-(trifluoromethyl)benzenaminium iodide
• Synonyms: N,N,N-trimethyl-4-(trifluoromethyl)benzenaminium iodide
• CAS NO: 27389-56-6
• Molecular Weight: 331.12
• Mol File: 27389-56-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N,N,N-trimethyl-4-(trifluoromethyl)benzenaminium iodide(CAS DataBase Reference)
• NIST Chemistry Reference: N,N,N-trimethyl-4-(trifluoromethyl)benzenaminium iodide(27389-56-6)
• EPA Substance Registry System: N,N,N-trimethyl-4-(trifluoromethyl)benzenaminium iodide(27389-56-6)

Safety Data

• Hazardous Substances Data: 27389-56-6(Hazardous Substances Data)

Upstream product

• 329-17-9 N,N-dimethyl-4-(trifluoromethyl)aniline 
• 74-88-4 methyl iodide 
• 455-14-1 4-trifluoromethylphenylamine 

Downstream Products

• 128796-39-4 4-trifluoromethylphenylboronic acid 
• 98-08-8 α,α,α-trifluorotoluene 
• 1006715-23-6 dimethyl(phenyl)(4-(trifluoromethyl)phenyl)silane 
• 329-17-9 N,N-dimethyl-4-(trifluoromethyl)aniline 
• 74-88-4 methyl iodide 
• 5396-38-3 1-(tert-butyl)-4-methoxybenzene 

Relevant articles and documents

Cross-Coupling of Organolithium with Ethers or Aryl Ammonium Salts by C?O or C?N Bond Cleavage

Various aryl-, alkenyl-, and/or alkyllithium species reacted smoothly with aryl and/or benzyl ethers with cleavage of the inert C?O bond to afford cross-coupled products, catalyzed by commercially available [Ni(cod)2] (cod=1,5-cyclooctadiene) catalysts with N-heterocyclic carbene (NHC) ligands. Furthermore, the coupling reaction between the aryllithium compounds and aryl ammonium salts proceeded under mild conditions with C?N bond cleavage in the presence of a [Pd(PPh3)2Cl2] catalyst. These methods enable selective sequential functionalizations of arenes having both C?N and C?O bonds in one pot.