27397-33-7Relevant academic research and scientific papers
Synthesis and reactions of tetracarbonylmanganese complexes of benzoylsilanes
Cambie, Richard C.,Mui, Linda Chua Mui,Rutledge, Peter S.,Woodgate, Paul D.
, p. 171 - 182 (1994)
Reactions of benzoylsilane with benzylpentacarbonylmanganese (1) give ortho-η2-manganese complexes in high yield.The derived aldehyde complex can then be formed by fluoride-catalysed desilylation of the acylsilane complex.Coupling reactions of the acylsilane complexes with alkenes or alkynes are reported. Key words: Manganese; Carbonyl; Silane; Aldehyde; Alkene; Alkyne
