Journal of Organometallic Chemistry p. 171 - 182 (1994)
Update date:2022-08-05
Topics:
Cambie, Richard C.
Mui, Linda Chua Mui
Rutledge, Peter S.
Woodgate, Paul D.
Reactions of benzoylsilane with benzylpentacarbonylmanganese (1) give ortho-η2-manganese complexes in high yield.The derived aldehyde complex can then be formed by fluoride-catalysed desilylation of the acylsilane complex.Coupling reactions of the acylsilane complexes with alkenes or alkynes are reported. Key words: Manganese; Carbonyl; Silane; Aldehyde; Alkene; Alkyne
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