27401-83-8

Basic information

• Product Name: (3-chlorophenyl)phenylmethyl methyl ether
• Synonyms: (3-chlorophenyl)phenylmethyl methyl ether
• CAS NO: 27401-83-8
• Molecular Weight: 232.71
• Mol File: 27401-83-8.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (3-chlorophenyl)phenylmethyl methyl ether(CAS DataBase Reference)
• NIST Chemistry Reference: (3-chlorophenyl)phenylmethyl methyl ether(27401-83-8)
• EPA Substance Registry System: (3-chlorophenyl)phenylmethyl methyl ether(27401-83-8)

Safety Data

• Hazardous Substances Data: 27401-83-8(Hazardous Substances Data)

Upstream product

• 625-99-0 3-iodochlorobenzene 
• 1125-88-8 benzaldehyde dimethyl acetal 
• 67-56-1 methanol 
• 13391-39-4 3-chlorobenzhydryl chloride 
• 156543-39-4 (3-chlorophenyl)phenylbromomethane 
• 115228-81-4 triphenyl(3-chlorophenyl)methane 

Relevant articles and documents

Dialkyl Ether Formation by Nickel-Catalyzed Cross-Coupling of Acetals and Aryl Iodides

A new substrate class for nickel-catalyzed C(sp3) cross-coupling reactions is reported. α-Oxy radicals generated from benzylic acetals, TMSCl, and a mild reductant can participate in chemoselective cross-coupling with aryl iodides using a 2,6-bis(N-pyrazolyl)pyridine (bpp)/Ni catalyst. The mild, base-free conditions are tolerant of a variety of functional groups on both partners, thus representing an attractive C-C bond-forming approach to dialkyl ether synthesis. Characterization of a [(bpp)NiCl] complex relevant to the proposed catalytic cycle is also described.

Kinetics and Mechanism of Reactions of Benzhydryl Chlorides with Anilines

Nucleophilic substitution reactions of substituted benzhydryl chlorides with anilines in acetonitrile and methanol are investigated.The reactions are found to proceed by the attack of nucleophile on the preformed carbocation, I, within the ion pair.The cr