2748-08-5

Upstream product

• 932-51-4 2,5-dimethylcyclohexanone 
• 3400-78-0 2-hydroxy-3-methyl-2-cyclohexen-1-one 
• 74-88-4 methyl iodide 
• 57493-09-1 3,6-bis-morpholin-4-ylmethyl-cyclohexane-1,2-dione 
• 110364-41-5 3-iodo-3,6-dimethyl-1,2-cyclohexanedione 
• 10316-66-2 2-hydroxy-2-cyclohexen-1-one 

Downstream Products

• 2913-41-9 3-hydroxy-2,5-dimethyl-[1,4]benzoquinone 
• 110364-43-7 4-iodo-3,6-dimethyl-1,2-benzenediol 
• 110364-44-8 3,3',4,4'-tetrahydroxy-2,2',5,5'-tetramethylbiphenyl 
• 110364-41-5 3-iodo-3,6-dimethyl-1,2-cyclohexanedione 

Relevant academic research and scientific papers

Photo-irradiation of α-halo carbonyl compounds: A novel synthesis of α-hydroxy- and α,α′-dihydroxyketones

The reaction of α-halo ketones (α-iodocycloalkanones, α-bromocycloalkanones, α-iodo-β-alkoxy esters, and α-iodoacyclicketones) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketones in good yields. For α-bromoketones, it was found that α-hydroxylation does not occur. However, α-bromoketones were converted into α-hydroxyketones in the presence of KI. In the case of α,α′-diiodo ketones, α,α′-dihydroxyketones, which up to now have scarcely been reported, were obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′- dihydroxyketones.

A novel synthesis of α-hydroxy- and α,α′- dihydroxyketone from α-iodo and α,α′-diiodo ketone using photoirradiation

A novel reaction of α-iodo ketone (α-iodocycloalkanone, α-iodo-β-alkoxy ester, and α-iodoacyclicketone) with irradiation under a high-pressure mercury lamp gave the corresponding α-hydroxyketone in good yields. In the case of α,α′- diiodo ketone, α,α′-dihydroxyketone which little has been reported until now was obtained. This reaction affords a new, clean and convenient synthetic method for α-hydroxy- and α,α′- dihydroxyketone.

A New Synthesis of 3-Alkyl-1,2-cyclohexanediones from 2-Alkylcyclohexanones Using Iodine/Copper(II) Acetate

The reactions of 2-alkyl-, 2,5-dimethyl-, and 3,3,5-trimethylcyclohexanone with iodine/copper(II) acetate in boiling aqueous acetic acid gave the respective 3-alkyl-, 3,6-dimethyl-, and 3,5,5-trimethyl-1,2-cyclohexanediones in 40-70percent yields.This new

REGIOSELECTIVE MONOALKYLATION OF 3-METHYL-1,2-CYCLOHEXANEDIONE

Monoalkylation of 3-methyl-1,2-cyclohexanedione was achieved regioselectively to give 6-alkyl-3-methyl-1,2-cyclohexanedione as a major product without the formation of O-alkylated or polyalkylated products.