27557-55-7Relevant academic research and scientific papers
The stereochemistry of 1,2-additions of allylmagnesium, allylindium, and allylbismuth to cyclohexenones
Zhao, Liang,Burnell, D.Jean
, p. 3291 - 3294 (2006)
Allylmagnesium, allylindium, and allylbismuth generally showed a preference for axial addition to cyclohexenones. Allylmagnesium was the most stereoselective. Reactions with an α-methylated enone (carvone) were the most selective, except that allylbismuth was unreactive with this substrate.
Synthesis of 2,2,-Disubstituted Oxetanes from Ketones with S-Methyl-S-(sodiomethyl)-N-(4-tolylsulfonyl)sulfoximine
Welch, Steven C.,Rao, A. S. C. Prakasa,Lyon, John T.,Assercq, Jean-Marie
, p. 252 - 257 (2007/10/02)
A covenient and facile one-step synthesis of 2,2-disubstituted oxetanes from ketones utilizing S-methyl-S-(sodiomethyl)-N-(4-tolylsulfonyl)sulfoxymine in dimethyl sulfoxide is presented.The stereochemistry and chemical reactivity of some 2,2-disubstituted
