27801-58-7

Basic information

• Product Name: Phenol, 2,4,6-tris(1,1-dimethylethyl)-, sodium salt
• CAS NO: 27801-58-7
• Molecular Formula: C18H30O.Na
• Molecular Weight: 284.417
• Mol File: 27801-58-7.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Phenol, 2,4,6-tris(1,1-dimethylethyl)-, sodium salt(CAS DataBase Reference)
• NIST Chemistry Reference: Phenol, 2,4,6-tris(1,1-dimethylethyl)-, sodium salt(27801-58-7)
• EPA Substance Registry System: Phenol, 2,4,6-tris(1,1-dimethylethyl)-, sodium salt(27801-58-7)

Safety Data

• Hazardous Substances Data: 27801-58-7(Hazardous Substances Data)

Upstream product

• 732-26-3 2,4,6-tri-tert-butylphenoxol 
• 7440-23-5 sodium 

Downstream Products

• 5457-60-3 4-chloro-2,4,6-tri-tert-butylcyclohexa-2,5-dienone 
• 134724-20-2 Neopentyl 2,4,6-tri-t-butylphenyl ether 
• 959930-21-3 C₆H₅PdP(C(CH₃)3)2C₁₀H₁₅OC₆H₂(C(CH₃)3)3 
• 895129-05-2 [(2,4,6-tri-tert-butyl-phenolate)Yb(BH₄)2(THF)2] 
• 895129-06-3 [(2,4,6-tri-tert-butyl-phenolate)Er(BH₄)2(THF)2] 
• 3315-32-0 2,4,6-tri-tert-butylphenoxyl 
• 26448-08-8 fluorodinitromethane anion 

Relevant articles and documents

N-Arylation of protected azamacrocycles

A rapid method for efficient palladium-catalyzed N-arylation of polynitrogenated macrocycles is presented. Its applicability for functionalization of protected azamacrocycles of various sizes with substituted aryl bromides of optional electronic properties is demonstrated. The compatibility of the protocol with common N-protecting schemes as well as the impact of electronic versus steric factors is discussed. Using a commercially available catalytic system and easily available alkoxide or phenoxide base, the method provides moderate to excellent yields of N-arylated azamacrocycles (45-96%). Georg Thieme Verlag Stuttgart · New York.