2783-26-8

Basic information

• Product Name: 2-(2-methylphenyl)oxirane
• Synonyms: 2-(2-methylphenyl)oxirane
• CAS NO: 2783-26-8
• Molecular Formula: C₉H₁₀O
• Molecular Weight: 134.1751
• Mol File: 2783-26-8.mol
• Article Data: 23

Chemical Properties

• Boiling Point: 218.9°Cat760mmHg
• Flash Point: 81.3°C
• Appearance: /
• Density: 1.075g/cm³
• Vapor Pressure: 0.182mmHg at 25°C
• Refractive Index: 1.556
• CAS DataBase Reference: 2-(2-methylphenyl)oxirane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(2-methylphenyl)oxirane(2783-26-8)
• EPA Substance Registry System: 2-(2-methylphenyl)oxirane(2783-26-8)

Safety Data

• Hazardous Substances Data: 2783-26-8(Hazardous Substances Data)

Usage

InChI:InChI=1/C9H10O/c1-7-4-2-3-5-8(7)9-6-10-9/h2-5,9H,6H2,1H3

Upstream product

• 2181-44-4 trimethylsulfonium methylsulfate 
• 529-20-4 2-methylphenyl aldehyde 
• 333-27-7 methyl trifluoromethanesulfonate 
• 593-71-5 Chloroiodomethane 
• 611-15-4 1-methyl-2-vinyl-benzene 
• 119391-23-0 C₁₆H₁₇N₂O₃S^(1-)*Na⁽¹⁺⁾ 
• 6814-64-8 methylenedimethyl sulfurane 
• 1774-47-6 trimethylsulfoxonium iodide 
• 2181-42-2 trimethylsulphonium iodide 

Downstream Products

• 77969-29-0 2-[2-(2-Chloro-3,4-dimethoxy-phenyl)-ethylamino]-1-o-tolyl-ethanol 
• 77969-43-8 6-Chloro-1-o-tolyl-2,3,4,5-tetrahydro-1H-benzo[d]azepine-7,8-diol; hydrobromide 
• 3217-93-4 N-phenylethylhydroxylamine 
• 62717-58-2 N-[2-(3,4-dimethoxyphenyl)ethyl]-2-hydroxy-2-(2-methylphenyl)ethylamine 
• 1009308-80-8 C₁₉H₂₁NO 
• 10166-08-2 2-methyl-benzeneacetaldehyde 
• 1166859-80-8 C₁₅H₂₃NO₅S 
• 1323143-09-4 C₉H₉⁽²⁾HO 
• 1179318-35-4 2-(o-tolyl)prop-2-en-1-ol 
• 1166859-58-0 (R)-3-(2-methylphenyl)-1,2-thiazolidine 1,1-dioxide 
• 1166859-51-3 3-(2-methylphenyl)-4,5-dihydro-isothiazole 1,1-dioxide 
• 1166859-81-9 C₁₅H₂₁NO₅S 

Relevant articles and documents

Kinetic resolution ofN-aryl β-amino alcoholsviaasymmetric aminations of anilines

An efficient kinetic resolution ofN-aryl β-amino alcohols has been developedviaasymmetricpara-aminations of anilines with azodicarboxylates enabled by chiral phosphoric acid catalysis. Broad substrate scope and high kinetic resolution performances were afforded with this method. Control experiments supported the critical roles of the NH and OH group in these reactions.

MeOTf-catalyzed formal [4?+?2] annulations of styrene oxides with alkynes leading to polysubstituted naphthalenes through sequential electrophilic cyclization/ring expansion

MeOTf-catalyzed formal [4 + 2] annulation of styrene oxides with alkynes to afford polysubstituted naphthalenes has been realized, which undergoes sequential electrophilic cyclization/ring expansion. A range of substrates were tolerated in the formation of naphthalene derivatives with high regioselectivity in satisfactory yields. The reaction could also be carried out on gram scale.

Pyrazine dicarboxylate-bridged arsenotungstate: Synthesis, characterization, and catalytic activities in epoxidation of olefins and oxidation of alcohols

A praseodymium(iii)-containing arsenotungstate K16H15Li7[Pr2(H2O)3(pzdc)As3W29O103]2·38H2O (1) (pzdc = pyrazine-2,3-dicarboxylic acid) was synthesized by a conventional aqueous solution method and characterized by elemental analysis, IR spectroscopy, thermogravimetric analysis (TGA), powder X-ray diffraction (PXRD), and single crystal X-ray diffraction. Structural analysis revealed that compound 1 was constructed by two identical subunits {Pr2(H2O)3(AsW9O33)3W2O4} bridged together by two pzdc ligands. In addition, compound 1 could act as an efficient catalyst for the epoxidation of olefins and oxidation of alcohols with hydrogen peroxide (H2O2) as the oxidant. In particular, the turnover frequency (TOF) in the oxidation of 1-phenylethanol reached up to 10170 h-1, which is higher than that of previously reported catalysts.