2788-26-3Relevant academic research and scientific papers
Preparation method of phosphine series reactive flame retardant monomer
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Paragraph 0060; 0061, (2019/02/27)
The invention provides a preparation method of a phosphine series reactive flame retardant monomer. The preparation method comprises the following steps: preparing a compound with a structure shown ina formula VI or a formula VII; under the action of alkaline solution, hydrolyzing the compound with the structure shown in the formula VI or the formula VII, then adding acid solution to regulate acid, then adding inorganic salt to carry out saturation processing, then adding an organic solvent to extract, and then performing evaporation drying on the organic solvent to obtain a compound with a structure shown in a formula VIII or a formula IX; adding a dehydrating agent into the compound with the structure shown in the formula VIII or the formula IX to enable the compound with the structureshown in the formula VIII or the formula IX to be dewatered and cyclized so as to obtain the phosphine series reactive flame retardant monomer with a structure shown in a formula I or a formula II. The preparation method of the phosphine series reactive flame retardant monomer, which is provided by the invention, is simple in process, high in reaction yield and simple and convenient to operate, does not need to use special equipment, is sufficient and reliable in source of raw materials, low in cost, environmentally friendly and suitable for industrial production.
Synthesis and hydrophosphorylation of π-complexes of Esters of unsaturated carboxylic acids with chromium subgroup metals
Kuramshin,Kuramshina,Cherkasov
, p. 864 - 872 (2007/10/03)
Photochemical and thermochemical activation were used to prepare new π-complexes of chromium, molybdenum and tungsten containing η2- and η4-coordinated methyl acrylate, methyl cynnamate, and dimethyl fumarate molecules. Geometric, el
ADDITIONS DES FONCTIONS >NH ET >P(O)H SUR LA DOUBLE LIAISON DES VINYL SPIROPHOSPHORANES SYNTHESE DES α ET β AMINO SPIROPHOSPHORANES ALCOOLYSE DE LA LIAISON P-C DANS LES COMPOSES D'ADDITION OBTENUS
Burgada, Ramon,Mohri, Ali
, p. 85 - 96 (2007/10/02)
Addition of amines and of hydrogenphosphonates on the carbon-carbon double bond belonging to vinylphosphoranes is examined.The stereochemistry and reactivity of the saturated adducts obtained is rationalized.Alcoholysis of the P-C bond is also studied.
