27962-47-6Relevant academic research and scientific papers
Photochemically Induced Single Electron Transfer Reactions of Benzils with Allylstannane. Direct Observation of Reactive Intermediates by ESR Method
Maruyama, Kazuhiro,Matano, Yoshihiro
, p. 2218 - 2223 (1990)
Allthough the photochemically induced reaction of benzil with allyltrimethylstannane in benzene afforded α-allylbenzoin as a major product, benzil did not react thermally with the same reagent.An ESR observation disclosed that the benzil anion radical ion
Palladium-catalyzed C-allylation of benzoins and an NHC-catalyzed three component coupling derived thereof: Compatibility of NHC- and Pd-catalysts
Lebeuf, Raphael,Hirano, Keiichi,Glorius, Frank
supporting information; experimental part, p. 4243 - 4246 (2009/06/06)
(Chemical Equation Presented) A large range of benzoins was successfully applied as C-nucleophiles in the palladium-catalyzed allylic alkylation with several allyl acetates, resulting in functionalized tertiary homoallylic alcohols. A number of unsymmetrical benzoins can be coupled with high levels of regio- and chemoselectivity. Finally, the challenging compatibility of free N-heterocyclic carbenes with a palladium catalyst has been utilized in a number of metal- and organocatalyzed three-component coupling reactions.
