27984-20-9

Basic information

• Product Name: 4-Penten-1-one, 2-methoxy-1,2-diphenyl-
• CAS NO: 27984-20-9
• Molecular Formula: C18H18O2
• Molecular Weight: 266.34
• Mol File: 27984-20-9.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 4-Penten-1-one, 2-methoxy-1,2-diphenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 4-Penten-1-one, 2-methoxy-1,2-diphenyl-(27984-20-9)
• EPA Substance Registry System: 4-Penten-1-one, 2-methoxy-1,2-diphenyl-(27984-20-9)

Safety Data

• Hazardous Substances Data: 27984-20-9(Hazardous Substances Data)

Upstream product

• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 107-05-1 3-chloroprop-1-ene 
• 74-88-4 methyl iodide 
• 24650-42-8 2,2-dimethoxy-2-phenylacetophenone 
• 72824-04-5 2-Allyl-4,4,5,5-tetramethyl-1,3,2-dioxaborolane 
• 5623-21-2 α-allylbenzoin 
• 80-18-2 Methyl benzenesulfonate 
• 3524-62-7 benzoin monomethyl ether 

Relevant articles and documents

Catalytic Use of Elemental Gallium for Carbon-Carbon Bond Formation

The first catalytic use of Ga(0) in organic synthesis has been developed by using a Ag(I) cocatalyst, crownether ligation, and ultrasonic activation. Ga(I)-catalyzed C-C bond formations between allyl or allenyl boronic esters and acetals, ketals, or aminals have proceeded in high yields with essentially complete regio- and chemoselectivity. NMR spectroscopic analyses have revealed novel transient Ga(I) catalytic species, formed in situ through partial oxidation of Ga(0) and B-Ga transmetalation, respectively. The possibility of asymmetric Ga(I) catalysis has been demonstrated.