27993-43-7

Basic information

• Product Name: 5-methyl-1-phenylhexan-2-one
• Synonyms: 5-methyl-1-phenylhexan-2-one
• CAS NO: 27993-43-7
• Molecular Weight: 190.285
• Mol File: 27993-43-7.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 5-methyl-1-phenylhexan-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methyl-1-phenylhexan-2-one(27993-43-7)
• EPA Substance Registry System: 5-methyl-1-phenylhexan-2-one(27993-43-7)

Safety Data

• Hazardous Substances Data: 27993-43-7(Hazardous Substances Data)

Upstream product

• 108-86-1 bromobenzene 
• 73503-97-6 5-methyl-2-(trimethylsiloxy)-1-hexene 
• 4548-78-1 (3-methylbutyl)magnesium bromide 
• 103-80-0 phenylacetyl chloride 
• 96206-34-7 5-methyl-1-phenylhex-4-en-2-ol 
• 4436-24-2 1,2-epoxy-3-phenylpropane 
• 542-54-1 isocapronitrile 
• 6921-34-2 benzylmagnesium chloride 
• 591-50-4 iodobenzene 
• 103-82-2 phenylacetic acid 
• 646-07-1 4-Methylpentanoic acid 

Relevant articles and documents

Photoinduced Remote Functionalisations by Iminyl Radical Promoted C?C and C?H Bond Cleavage Cascades

A photoinduced cascade strategy leading to a variety of differentially functionalised nitriles and ketones has been developed. These reactions rely on the oxidative generation of iminyl radicals from simple oximes. Radical transposition by C(sp3)?(sp3) and C(sp3)?H bond cleavage gives access to distal carbon radicals that undergo SH2 functionalisations. These mild, visible-light-mediated procedures can be used for remote fluorination, chlorination, and azidation, and were applied to the modification of bioactive and structurally complex molecules.

Regioselective Arylation of Silyl Enol Ethers of Methyl Ketones with Aryl Bromides

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