280-65-9Relevant academic research and scientific papers
Chemoselectivity of Nitroxylation of Cage Hydrocarbons
Ivleva, E. A.,Klimochkin, Yu. N.,Leonova, M. V.
, p. 1702 - 1710 (2020/12/01)
Abstract: The composition of reaction mixtures obtained by nitroxylation of 13 cage hydrocarbons with 100% nitric acid and its mixtures with acetic acid, acetic anhydride, and methylene chloride has been studied. More reactive substrates react with lowest
Cyclisation of 5-Bromomethyl-cycloheptene and -cyclo-octene: a New Route to Bicyclooctanes and Bicyclononanes
MacCorquodale, Finlay,Walton, John C.
, p. 347 - 352 (2007/10/02)
Reduction of 5-(bromomethyl)cycloheptene with tributyltin hydride gave bicyclooctane; similar reduction of 5-(bromomethyl)cyclo-octene gave bicyclononane together with some bicyclononane.The cyclohept-4-enylmethyl radical intermediate
Formation of Bicyclooctane, Bicyclononane, and Bicyclononane by Transannular Radical Cyclisations
MacCorquodale, Finlay,Walton, John C.
, p. 1456 - 1457 (2007/10/02)
Cyclohept-4-enylmethyl radicals undergo transannular cyclisation to give bicyclooctane; likewise, bicyclononane and bicyclononane are obtained from cyclo-oct-4-enylmethyl radicals.
Photochemistry of Alkyl Halides. 8. Formation of a Bridgehead Alkene
Kropp, Paul J.,Worsham, Paul R.,Davidson, Robert I.,Jones, Tappey H.
, p. 3972 - 3980 (2007/10/02)
Irradiation of the bridgehead iodides 4,7,and 10 afforded principally the ionic products 6,9,and 12 accompanied by small amounts of the reduction products 5, 8, and 11.Studies in methanol-d indicated an absence of pathways leading to ethers 6, 9, and 12 i
