28023-86-1

Upstream product

• 98124-30-2 1-oxido-2-triphenylphosphonio-3,5-diphenylbenzene 
• 7028-41-3 5-phenylresorcinol 
• 71-43-2 benzene 
• 6265-29-8 3-ethoxycarbonyl-4,6-diphenyl-2,6-hexanedione 
• 94-02-0 ethyl 3-oxo-3-phenylpropionate 
• 1817-57-8 4-phenyl-3-butyne-2-one 

Downstream Products

• 103068-20-8 1-bromo-3,5-diphenylbenzene 
• 116941-51-6 4-chloro-5′-phenyl-1,1′:3′,1″-terphenyl 
• 343239-58-7 5′-phenyl-[1,1′:3′,1″-terphenyl]-4-amine 
• 1141802-52-9 LUF₆₁₉₂ 
• 1141802-32-5 LUF₆₁₉₈ 
• 1141802-29-0 LUF₆₁₉₇ 

Relevant academic research and scientific papers

Synthesis of di- and poly-substituted phenols via [4 + 2] type cyclo-condensation

A new [4 + 2] type cyclocondensation was developed to prepare 3,5- and poly-substituted phenols using aryl ketoesters and ynones as the starting materials; Various substrates, such as aryl-, heteroaryl ketoesters and aryl-, vinyl-, alkyl substituted ynones, were employed. In addition, extending the substrate scope to benzoyl acetone provided 3,4,5-trisubstituted phenols.

DBU-Catalyzed Michael Reaction of Enones with 1,3-Diketones and the Subsequent Iodine-Mediated Transformation of the Adducts to Polysubstituted Phenols

An efficient DBU-catalyzed Michael reaction of enones with 1,3-diketones has been developed for the gram-scale preparation of the Michael adducts. It is attractive that most of the adducts can be obtained with high purity through simple filtration. A conv

A NEW METHOD FOR THE SYNTHESIS OF 3,5-DIARYLPHENOLS

Reaction of the diylide containing a triphenylphosphonium and pyridinium group at position 1,3 with α,β-unsaturated ketones leads to the formation of 1-oxido-2-triphenylphosphonio-3,5-diarylbenzenes.Their subsequent hydrolysis leads to 3,5-diarylphenols.

REACTION OF PHENOLS AND THEIR DERIVATIVES WITH AROMATIC COMPOUNDS IN THE PRESENCE OF ACIDIC AGENTS IV. CONDENSATION OF SUBSTITUTED RESORCINOLS WITH BENZENE AND CHLOROBENZENE

In the presence of aluminium chloride 5-methyl-, 5-phenyl, and 5- and 4-chlororesorcinols are brought into condensation with benzene through positions 5 or 3, depending on the nature of substituent.