6265-29-8Relevant articles and documents
Reaction between Chalcones, 1,3-Dicarbonyl Compounds, and Elemental Sulfur: A One-Pot Three-Component Synthesis of Substituted Thiophenes
Adib, Mehdi,Rajai-Daryasarei, Saideh,Pashazadeh, Rahim,Jahani, Mehdi,Amanlou, Massoud
, p. 1583 - 1588 (2018/06/11)
A simple and atom-economic synthesis of highly substituted thiophenes is demonstrated. Heating a solution of a chalcone and a linear/cyclic 1,3-dicarbonyl compound with elemental sulfur in CH 3 CN in the presence of NEt 3 at 80 °C af
Novel and versatile solid superbases derived from magnesium-zirconium composite oxide and their catalytic applications
Zhao, Jin,Xie, Jun,Au, Chak-Tong,Yin, Shuang-Feng
, p. 6159 - 6164 (2014/01/23)
Versatile solid superbases were derived from magnesium-zirconium composite oxide and KOH through thermal treatment in a N2 flow. The magnesium-zirconium composite oxide was prepared by a modified co-precipitation technique with reflux-digestion in basic solution and then mixed with KOH through grinding. The as-prepared solid superbases were characterized by low-temperature N2 physisorption, powder X-ray diffraction, and Fourier transformation infrared spectrophotometry. The superbasic sites were characterized by the use of Hammett indicators and CO2 temperature-programmed desorption methods. We found that there are ample superbasic sites (0.590 mmol g-1) on the surface with strength in the 26.5 ≤ H- 33.0 range. The as-prepared solid superbase catalyst was found to show excellent catalytic activity towards Knoevenagel condensation, Michael addition and transesterification reactions. The findings open up a new route for the synthesis of new functional superbases using composite oxides prepared by reflux-digestion in basic solution as supports.
Polyaniline-Anchored Metal Salts for Michael Reaction of ,-Unsaturated Ketones
Patel, Arun L.,Talele, Harish R.,Rama,Bedekar, Ashutosh V.
scheme or table, p. 3016 - 3023 (2009/12/01)
A catalyst consisting of polyaniline-anchored metal salts is used as a Lewis acid to promote the Michael reaction of ,-unsaturated ketones. The reaction is performed efficiently with imidazole, acetyl acetone, and ethyl acetate as Michel donors and chalcones as the acceptors under ultrasound irradiation.