28046-69-7Relevant academic research and scientific papers
Syntheses and conformational analyses of mono- and trans-1,4-dialkoxy substituted cyclohexanes-the steric substituent/skeleton interactions
Kleinpeter, Erich,Thielemann, J?rg
, p. 9071 - 9081 (2008/02/09)
Mono- and trans-1,4-dialkoxy substituted cyclohexanes (alkyl=Me, Et, i-Pr, t-Bu) were prepared using the solvomercuration-demercuration (SM-DM) procedure. The axial?axial and axial,axial?equatorial, equatorial conformational equilibria of the products wer
Three Component Reactions. XX. Methoxymercuration of Cyclohexa-1,4-dienes
Beger, J.,Thomas, B.,Vogel, T.,Lang, R.
, p. 447 - 453 (2007/10/02)
The methoxymercuration of several cyclohexa-1,4-dienes leads to insoluble mixtures of mono- and bismercuricompounds 2-4 and 5-7.After reduction with NaBH4/NaOH mixtures of methoxycyclohexenes and bismethoxycyclohexanes result.The result of capillary gaschromatographic analyses and n.m.r. spectra allows a semiquantitative evaluation of the reaction pathways.
