2815-45-4Relevant articles and documents
Selective homologation of ketones and aldehydes with diazoalkanes promoted by organoaluminum reagents
Maruoka,Concepcion,Yamamoto
, p. 1283 - 1290 (2007/10/02)
Organoaluminum-promoted single homologation or ring expansion of ketones and aldehydes with diazoalkanes has been described, and among various organoaluminium reagents, exceptionally bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective homologation of various ketones and aldehydes.
NOVEL ONE STEP SYNTHESIS OF EPOXIDES FROM β-HYDROXY-SELENIDES AND SULFIDES
Laboureur, J. L.,Dumont, W.,Krief, A.
, p. 4569 - 4572 (2007/10/02)
Epoxides are stereoselectively prepared in one step from β-hydroxy selenides and β-hydroxy sulfides in a process which involves dichlorocarbene