2815-45-4

Usage

InChI:InChI=1/C11H20O/c1-10(2,3)9-4-6-11(7-5-9)8-12-11/h9H,4-8H2,1-3H3

Upstream product

• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 92799-79-6 α-hydroperoxy-α-methoxyacetophenone 
• 54724-66-2 4-tert-Butyl-1-(phenylselenomethyl)-cyclohexanol 
• 186581-53-3 diazomethane 
• 98-53-3 4-tercbutyl-cyclohexanone 

Downstream Products

• 79392-44-2 bis-(2-ethyl-hexyl)-disulfane 
• 63615-83-8 Hexahydro-benzothiazol-2-one 
• 83048-89-9 t-6-t-butyl-1-thiaspiro<2.5>octane 
• 83062-60-6 2-<(4-t-butylcyclohexylmethylene)thio>-cis-3a,4,5,6,7a-hexahydrobenzothiazole 
• 83062-58-2 cis-2-<(r-1-hydroxy-4-t-butylcyclohexylmethyl)thio>-cis-3a,4,5,6,7a-hexahydrobenzothiazole 
• 83062-58-2 trans-2-<(r-1-hydroxy-4-t-butylcyclohexylmethyl)thio>-cis-3a,4,5,6,7a-hexahydrobenzothiazole 
• 183-84-6 Cyclohexanone diperoxide 
• 108-94-1 cyclohexanone 
• 121744-27-2 3-tert-Butyl-7,8,15-trioxa-dispiro[5.2.5.2]hexadecane 
• 16204-37-8 3,6-diphenyl-1,2,4,5-tetraoxane 
• 121744-26-1 9-tert-Butyl-3-phenyl-1,2,4-trioxa-spiro[5.5]undecane 
• 121744-28-3 3,12-Di-tert-butyl-7,8,15-trioxa-dispiro[5.2.5.2]hexadecane 
• 98-53-3 4-tercbutyl-cyclohexanone 
• 6353-54-4 4-tert-butyl-1-methylcyclohexanol 

Relevant academic research and scientific papers

Selective homologation of ketones and aldehydes with diazoalkanes promoted by organoaluminum reagents

Organoaluminum-promoted single homologation or ring expansion of ketones and aldehydes with diazoalkanes has been described, and among various organoaluminium reagents, exceptionally bulky methylaluminum bis(2,6-di-tert-butyl-4-methylphenoxide) (MAD) is found to be highly effective for the selective homologation of various ketones and aldehydes.

Oxidation of Alkenes and Sulphides with a Series of Hydroperoxides having Electron-withdrawing Substituents at the α-Position

The oxidations of alkenes and sulphides with a series of hydroperoxides, α-hydroperoxy-α-methoxyacetophenone (1), α-hydroperoxy-α,α-diphenylacetophenone (2), methyl α-hydroperoxy-α,α-diphenylacetate (3), and α-hydroperoxy-α,α-diphenylacetonitrile (4), were undertaken in a systematic fashion.The data revealed the following. (a) The reactions of electron-rich alkenes (11a and b) with hydroperoxides (1)-(4) are most likely to proceed by a mechanism similar to that with peracids, as do the oxidations of sulphides (5a-e). (b) For the reaction of less reactive alkenes (11f-k) with hydroperoxide (1) in the presence of oxygen, epoxidation by benzoylperoxyl radical contributes to a significantextent.The reaction with hydroperoxide (2) at 60 deg C also seems to proceed by a mechanism involving benzoylperoxyl radical, whereas a molecular epoxidation mechanism is important for the reaction at 30 deg C.Perhaps in accord with this, the reaction of 1,1-disubstituted ethylenes (11c-e) with hydroperoxides (1) and (2) results in the formation of considerable amounts of benzoylated products (13) and (14). (c) For the epoxidation with hydroperoxides (3) and (4), however, a molecular epoxidation process seems to predominate.The exception is the reaction of hydroperoxide (3) with (Z)-2-phenylbut-2-ene and (Z)-stilbene, having very poor reactivity, in which a peroxyl radical, produced by hydrogen abstraction from the hydroperoxide (3), plays an important role in the epoxidation.

NOVEL ONE STEP SYNTHESIS OF EPOXIDES FROM β-HYDROXY-SELENIDES AND SULFIDES

Epoxides are stereoselectively prepared in one step from β-hydroxy selenides and β-hydroxy sulfides in a process which involves dichlorocarbene