16980-56-6

Basic information

• Product Name: 4-tert-butyl-1-methylcyclohexanol
• CAS NO: 16980-56-6
• Molecular Formula: C₁₁H₂₂O
• Molecular Weight: 170.2918
• Mol File: 16980-56-6.mol
• Article Data: 24

Chemical Properties

• Boiling Point: 213.6°C at 760 mmHg
• Flash Point: 85.9°C
• Density: 0.905g/cm³
• Vapor Pressure: 0.036mmHg at 25°C
• Refractive Index: 1.465
• CAS DataBase Reference: 4-tert-butyl-1-methylcyclohexanol(CAS DataBase Reference)
• NIST Chemistry Reference: 4-tert-butyl-1-methylcyclohexanol(16980-56-6)
• EPA Substance Registry System: 4-tert-butyl-1-methylcyclohexanol(16980-56-6)

Safety Data

• Hazardous Substances Data: 16980-56-6(Hazardous Substances Data)

Upstream product

• 98-53-3 4-tercbutyl-cyclohexanone 
• 5951-21-3 cis-1,2-Epoxy-1-methyl-4-tert-butylcyclohexane 
• 75-16-1 methylmagnesium bromide 
• 2815-45-4 6-tert-butyl-1-oxaspiro[2.5]octane 
• 104331-98-8 4-tert-Butyl-1-methylselanylmethyl-cyclohexanol 
• 917-54-4 methyllithium 
• 18006-13-8 methyltriisopropoxytitanium(IV) 
• 2747-38-8 methyltrichlorotitanium 
• 917-64-6 methyl magnesium iodide 
• 7787-78-2 6-tert-Butyl-1-oxa-spiro[2.5]octane 
• 676-58-4 methylmagnesium chloride 
• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 104331-99-9 4-tert-Butyl-1-methylselanylmethyl-cyclohexanol 
• 18881-26-0 (3r,6r)-6-(tert-butyl)-1-oxaspiro[2.5]octane 

Downstream Products

• 3419-74-7 4-tert-Butyl-1-methylcyclohex-1-en 
• 25276-12-4 4-tert-butyl-1-methylcyclohexyl bromide 
• 25276-11-3 4-tert-butyl-1-methylcyclohexyl bromide 
• 19311-30-9 4-tert-butyl-1-methylcyclohexyl chloride 
• 37446-10-9 1α-Methyl-4β-t-butylcyclohexyl-2,4-dinitrophenolat 
• 37446-11-0 1α-Methyl-4α-t-butylcyclohexyl-2,4-dinitrophenolat 
• 343853-71-4 4-tert-butyl-1-methylcyclohexanol methyl ether 
• 13294-73-0 1-tert-butyl-4-methylenecyclohexane 
• 25276-10-2 cis-4-t-butyl-1-methylcyclohexyl chloride 
• 32384-11-5 N-(trans-4-tert-butyl-1-methylcyclohexyl)formamide 
• 32384-10-4 N-(cis-4-tert-butyl-1-methylcyclohexyl)formamide 

Relevant articles and documents

Influence of Alcohol β-Fluorination on Hydrogen-Bond Acidity of Conformationally Flexible Substrates

Rational modulations of molecular interactions are of significant importance in compound properties optimization. We have previously shown that fluorination of conformationally rigid cyclohexanols leads to attenuation of their hydrogen-bond (H-bond) donat

Facial Stereoselectivity of Two-Step Additions Initiated by Electrophilic Halogens to Methylenecyclohexanes. A Comparison with Epoxidation

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Sterically Crowded Aryloxide Compounds of Aluminium: Hydrides and Homoleptic Aryloxides

Interaction of and with HOR1 (R1 = C6H2But2-2,6-Me-4) allows for the isolation of 1)(NMe3)> 1 and 1)(NMe3)> 2 respectively.Compound 1 exists in both mono- and di-meric forms in the solid state.The reaction of 1 with NH2But results in ligand redistribution to give 1)2(NH2But)> 3.Similarly, multiple recrystallisation of 1 from Et2O allows for the isolation of 1)2(OEt2)> 4, while addition of HOR2 (R2 = C6H3Ph2-2,6) to 1 yields the mixed aryloxide complex 1)(OR2)(NMe3)> 5.Interaction of compound 1 with benzophenone results in the formation of the bridged dimer 1)(μ-OCHPh2)>2> 6.The reaction of 3 molar equivalents of HOR1 with LiAlH4 yields, in addition to 1)(OEt2)>2>, compound 4, which reacts further with H2O, HOR1 or NH2C6H2Cl3-2,4,6 to give 1)2>2> 7, 1)3> 8 or 1)2(NHC6H2Cl3-2,4,6)> 13 respectively.Compounds 8 and 13 form stable Lewis acid-base complexes 1)3L> t-4 12> and 1)2(NHC6H2Cl3-2,4,6)L> (L = Et2O 14, py 15 or 3,5-dimethylpyridine 16).The presence of a slow ligand exchange for compounds 9 and 12 was investigated by 1H NMR spectroscopy.The molecular structures of 1, 3, 4, 8 and 12 have been confirmed by X-ray crystallography.