28151-59-9

Basic information

• Product Name: Benzene, 1-[(3-chloro-2-propenyl)sulfonyl]-4-methyl-, (Z)-
• CAS NO: 28151-59-9
• Molecular Formula: C10H11ClO2S
• Molecular Weight: 230.715
• Mol File: 28151-59-9.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1-[(3-chloro-2-propenyl)sulfonyl]-4-methyl-, (Z)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-[(3-chloro-2-propenyl)sulfonyl]-4-methyl-, (Z)-(28151-59-9)
• EPA Substance Registry System: Benzene, 1-[(3-chloro-2-propenyl)sulfonyl]-4-methyl-, (Z)-(28151-59-9)

Safety Data

• Hazardous Substances Data: 28151-59-9(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 78473-63-9 (3-chloro-propenyl)-p-tolyl sulfone 
• 542-75-6 E/Z-1,3-Dichloropropene 
• 824-79-3 sodium 4-methylbenzenesulfinate 
• 54646-53-6 (E)-3-chloro-1-propenyl p-tolyl sulfone 
• 135908-05-3 2-hydroxy-3-chloropropyl p-toluenesulfonate 
• 41411-59-0 3-(toluene-4-sulfonyl)-allyl alcohol 
• 95314-83-3 (E)-3-(p-toluenesulfonyl)-2-propene-1-ol 
• 1950-78-3 p-toluenesulfonyl iodide 
• 10061-02-6 (E)-1,3-dichloro-prop-1-ene 
• 798547-88-3 (2,3-dichloro-propyl)-p-tolyl sulfone 
• 158588-52-4 1-chloro-2-iodo-3-tosylpropane 

Downstream Products

• 28005-38-1 2-ethoxy-1-chloro-3-(toluene-4-sulfonyl)-propane 

Relevant articles and documents

A novel method for the construction of a benzene ring: A facile ring-closing reaction of (1E,3E,5E)-1-chloro-3-(p-tolylsulfonyl)-1,3,5-alkatrienes

(1E,3E,5E)-1-Chloro-3-(p-tolylsulfonyl)-1,3,5-alkatrienes (1) underwent facile ring-closure followed by spontaneous removal of hydrogen chloride to form a benzene ring. This reaction sequence occurred at relatively low temperature.

"Syn-Effect" in the Conversion of (E)-Vinylic Sulfones to the Corresponding Allylic Sulfones

It was found that (E)-vinylic sulfones preferentially afford (Z)-allylic sulfones as kinetically-controlled products by treatment with a base under mild conditions, while (Z)-vinylic sulfones give (E)-allylic sulfones.Such stereochemical relationship was