28237-96-9

Basic information

• Product Name: [bis-(p-methoxybenzoyloxy)iodo]benzene
• Synonyms: [bis-(p-methoxybenzoyloxy)iodo]benzene
• CAS NO: 28237-96-9
• Molecular Weight: 506.294
• Mol File: 28237-96-9.mol

Chemical Properties

• CAS DataBase Reference: [bis-(p-methoxybenzoyloxy)iodo]benzene(CAS DataBase Reference)
• NIST Chemistry Reference: [bis-(p-methoxybenzoyloxy)iodo]benzene(28237-96-9)
• EPA Substance Registry System: [bis-(p-methoxybenzoyloxy)iodo]benzene(28237-96-9)

Safety Data

• Hazardous Substances Data: 28237-96-9(Hazardous Substances Data)

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 100-09-4 4-methoxybenzoic acid 

Downstream Products

• 4181-97-9 phenyl 4-methoxybenzoate 
• 1266606-37-4 C₂₉H₂₉NO₆ 
• 1225446-59-2 4-methoxybenzoic acid 2,2-dimethyl-5-nitroso-[1,3]dioxan-5-yl ester 
• 1225446-65-0 4-methoxybenzoic acid (5-(4-methoxybenzoyl)-2,2-dimethyl-[1,3]dioxan-5-yl-ONN-azoxy)-2,2-dimethyl-[1,3]dioxan-5-yl ester 
• 7465-87-4 N-benzyl-4-methoxybenzamide 
• 791-28-6 Triphenylphosphine oxide 
• 121-98-2 methyl 4-methoxybenzoate 
• 113779-40-1 1-propynyl 4-methoxybenzoate 

Relevant articles and documents

C–H Acyloxylation of Polycyclic Aromatic Hydrocarbons

The C–H acyloxylation of polycyclic aromatic hydrocarbons (PAHs) is described. This reaction constructs aryl acyloxylate scaffolds from PAHs with equimolar hypervalent iodine compounds under mild reaction conditions. Interestingly, the blue light irradiat

An Efficient Approach to Functionalized Indoles from λ3-Iodanes via Acyloxylation and Acyl Transfer

Versatile role of λ3-iodanes has been identified between the reaction of hydroquinone and β-enaminones for the synthesis of 5-acyloxy-4-hydroxy indoles. The reaction is proposed to proceed through an intermolecular C?C bond formation, intramole

λ3-Iodanes as Visible Light Photocatalyst in Thioacetalization of Aldehydes

Introduction of an iodine(III) reagent as visible-light photocatalyst for chemoselective dithioacetalization has been the limelight of the current methodology. The mechanistic investigations reveal that the reactions proceeded via radical pathway upon lig

Preparation method and device for iodobenzene dibenzoate derivative

The invention relates to a preparation method and device for an iodobenzene dibenzoate derivative. The method includes the steps that 6 mmol of iodobenzene diacetate and 12 mmol of benzoic acid or a benzoic acid derivative or pivalic acid are added into a

Palladium catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates

A palladium-catalyzed ortho-C-H-benzoxylation of 2-arylpyridines using iodobenzene dibenzoates has been developed. The reaction employed the stable and easily accessible hypervalent iodine reagents as both benzoxylate source and oxidant which made the protocol simple and facile. It showed high regioselectivity and good functional group tolerance, and gave the mono-benzoxylation products in moderate to excellent yields.

α-Acyloxynitroso dienophiles in [4+2] hetero Diels-Alder cycloadditions: mechanistic insights

α-Acyloxynitroso derivatives are a class of heterodienophiles leading to valuable 3,6-dihydro-1,2-oxazines or the corresponding aminoalcohols in good yields. The discovery that a β-oxygenated moiety led to a domino [4+2] cycloaddition/σN-O bond cleavage in the presence of a catalytic amount of Lewis acid was investigated in detail, through kinetic profiling of the reaction both in the absence and presence of a promoter. These studies showed that the role of the Lewis acid was to accelerate the σN-O bond cleavage thereby promoting a highly reproducible sequence. In addition, our preliminary results on an asymmetric version of this domino sequence are reported.