4181-97-9

Basic information

• Product Name: 4-METHOXY-BENZOIC ACID PHENYL ESTER
• Synonyms: 4-METHOXY-BENZOIC ACID PHENYL ESTER;Anisalol;Anisic acid phenyl ester;p-Anisic acid phenyl ester;Phenyl 4-Methoxybenzoate
• CAS NO: 4181-97-9
• Molecular Formula: C₁₄H₁₂O₃
• Molecular Weight: 228.24328
• Mol File: 4181-97-9.mol
• Article Data: 78

Chemical Properties

• Melting Point: 73.7 °C
• Boiling Point: 367.7°C at 760 mmHg
• Flash Point: 153.9°C
• Appearance: /
• Density: 1.159g/cm³
• Vapor Pressure: 1.34E-05mmHg at 25°C
• Refractive Index: 1.569
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility: Chloroform (Slightly), DMSO (Slightly)
• CAS DataBase Reference: 4-METHOXY-BENZOIC ACID PHENYL ESTER(CAS DataBase Reference)
• NIST Chemistry Reference: 4-METHOXY-BENZOIC ACID PHENYL ESTER(4181-97-9)
• EPA Substance Registry System: 4-METHOXY-BENZOIC ACID PHENYL ESTER(4181-97-9)

Safety Data

• Hazardous Substances Data: 4181-97-9(Hazardous Substances Data)

Usage

Uses

Phenyl 4-Methoxybenzoate is a useful reagent for the synthesis of pyrazoles via iodine catalyzed denitrative imino-diaza-Nazarov cyclization.Phenyl 4-Methoxybenzoate is a potent inhibitor of of 15-lipoxygenase.

InChI:InChI=1/C14H12O3/c1-16-12-9-7-11(8-10-12)14(15)17-13-5-3-2-4-6-13/h2-10H,1H3

Upstream product

• 100-07-2 4-methoxy-benzoyl chloride 
• 108-95-2 phenol 
• 100-09-4 4-methoxybenzoic acid 
• 164594-13-2 Phenyl[2-(trimethylsilyl)phenyl]iodonium trifluoromethanesulfonate 
• 106-41-2 4-bromo-phenol 
• 107915-69-5 N-(4-methoxybenzoyl) saccharin 
• 98-80-6 phenylboronic acid 
• 6343-26-6 1-(4-Methoxybenzoyl)pyrrolidine-2,5-dione 
• 201230-82-2 carbon monoxide 
• 17763-67-6 Phenyl triflate 
• 150-76-5 4-methoxy-phenol 
• 3468-53-9 phenyl nicotinate 
• 696-62-8 para-iodoanisole 
• 104-92-7 1-bromo-4-methoxy-benzene 

Downstream Products

• 27410-09-9 3-(p-Anisyl)-1,4-pentadiin-3-ol 
• 611-99-4 4,4'-Dihydroxybenzophenone 
• 63084-03-7 6-methoxy-2-[(4-methoxyphenyl)carbonyl]-2,3,4-trihydronaphthalen-1-one 
• 63119-40-4 1-oxo-2-(4-methoxybenzoyl)-5-methoxyindane 
• 121-98-2 methyl 4-methoxybenzoate 
• 23886-71-7 4-methoxy-4'-methylbenzophenone 
• 874-90-8 4-methoxybenzonitrile 
• 75059-30-2 3,5-bis(4-methoxiphenyl)-1H-pyrazole 
• 37613-37-9 3-(4-fluorophenyl)-5-(4-methoxyphenyl)-1H-pyrazole 
• 46318-58-5 4-methoxybenzoylnitromethane 
• 16114-90-2 <(4-methoxyphenyl)methyl>diphenylphosphine oxide 
• 40715-68-2 1‐methoxy‐4‐(3‐phenylpropyl)benzene 
• 71501-17-2 1,4-bis(4-methoxyphenyl)butan-1-one 
• 4741-73-5 1,3-bis(4-methoxyphenyl)propane 

Relevant articles and documents

Transesterification kinetics investigation of r-substituted phenyl benzoates with 4-methoxyphenol in the presence of K2CO3 in DMF

Transesterification of R-substituted phenyl benzoates 1-5 with 4-methoxyphenol 6 was kinetically investigated in the presence of K 2CO3 in dimethylformamide (DMF) at various temperatures. The Hammett plots for the reactions of the 1-

Palladium Catalyzed Regioselective Cyclization of Arylcarboxylic Acids via Radical Intermediates with Diaryliodonium Salts

Palladium-catalyzed C2-arylation/intramolecular acylation with arylcarboxylic acids was developed by using diaryliodonium salts. The protocol has the advantage of good step-economy by two chemical bonds formation in one pot.

Transition-Metal-Free DMAP-Mediated Aromatic Esterification of Amides with Organoboronic Acids

A new, transition-metal-free, effective method for aromatic esterification of amides with organoboronic acids has been developed. A wide range of benzoate derivatives were obtained with yields ranging from moderate to good. The catalytic reaction shows a broad substrate scope and excellent functional group tolerance. Conceptually, DMAP mediates the reaction and is crucial for this transformation.