2825-68-5Relevant academic research and scientific papers
Structure and absolute configuration of mycobactin J
Schwartz, Brett D.,De Voss, James J.
, p. 3653 - 3655 (2001)
Mycobactin J 1 is a commercially available siderophore isolated from Mycobacterium avium subsp. paratuberculosis. There are discrepancies between previous reports of its structure and none have addressed its absolute configuration. We report here the complete structure and stereochemistry of mycobactin J, along with methodology to enable the determination of the absolute configuration of other mycobactins on a small scale.
Total Synthesis of the Proposed Structure of Mycobactin J
Ghosh, Chiranjit,Pal, Sujit,Patel, Akanksha,Kapur, Manmohan
supporting information, p. 6511 - 6515 (2018/10/20)
The total synthesis of the proposed structure of mycobactin J (MJ), a metabolite of Mycobacterium tuberculosis, is presented. The highlights of the synthesis include a careful control of the Z-stereochemistry of the unsaturated long chain fatty acid, a biomimetic construction of the oxazoline building block and the carriage of an unprotected phenol throughout the synthesis.
Phosphonium Iodide in Organic Synthesis
Chatterjea, J. N.,Majee, R. N.,Mukherjee, S. N.
, p. 733 - 735 (2007/10/02)
Phosphonium iodide is found useful in the stereospecific conversion of some vicinal diols to olefins.Synthesis of cis-hexadec-9-enolide has been achieved.
