282527-93-9Relevant academic research and scientific papers
Preparation and characterization of inclusion complex of carbosilane dendrimers and cyclodextrins
Zhu, Lin,Liu, Huashi,Guan, Ruifang,Zhou, Chuanjian
, p. 8775 - 8779 (2013/11/06)
In this paper, 1st-4th generation of carbosilane dendrimers [G 1(PhBr)-G4(PhBr)] were synthesized with bromophenyl group as a core molecule. Then, the inclusion reaction of α-, β-, γ-cyclodextrin and four generations of carbosilane d
The preparation of a new kind of carbosilane dendrimer with 4-(naphthalen-1-yl)phenyl core - An application of Suzuki coupling reaction
Zhou, Chuan-Jian,Guan, Rui-Fang,Feng, Sheng-Yu,Berg, David J.,Stobart, Stephen R.
, p. 947 - 952 (2007/10/03)
Using the divergent method, carbosilane dendrimers with p-bromophenyl core were synthesized by using alternating Grignard and hydrosilylation reactions. And then, α-naphthalenyl was connected to the core by using Suzuki coupling reaction. This gave a new carbosilane dendrimer with a 4-(naphthalen-1-yl)phenyl core. All the products were characterized by IR, 1HNMR, 13CNMR, 29SiNMR, and MS. The study shows that Suzuki Coupling reaction is an effective and powerful core- functionalization method and a satisfactory result can be achieved through prolonging the reaction time.
Modular Construction of Dendritic Carbosilanes. Organization of Dendrimer Connectivity around Bifunctional Precursors That Are Adapted for Sequential Convergent and Divergent Propagative Steps
Casado, Miguel Angel,Stobart, Stephen R.
, p. 1549 - 1552 (2007/10/03)
(Matrix Presented) Rdend = -CH2(CH2)2Si(Me)[CH2(CH 2)2Si(Me)(CH2CH=CH2) 2]2 Regiospecific hydrosilylation of 1-bromo-4-(prop-2-enyl)benzene offers an efficient route to molecular building block precursors that can accommodate sequential divergent and convergent steps for dendritic extension, establishing a modular methodology for assembly and organization of connectivity used for synthesis of modified carbosilane dendrimers including 14.
