81744-85-6Relevant academic research and scientific papers
The preparation of a new kind of carbosilane dendrimer with 4-(naphthalen-1-yl)phenyl core - An application of Suzuki coupling reaction
Zhou, Chuan-Jian,Guan, Rui-Fang,Feng, Sheng-Yu,Berg, David J.,Stobart, Stephen R.
, p. 947 - 952 (2005)
Using the divergent method, carbosilane dendrimers with p-bromophenyl core were synthesized by using alternating Grignard and hydrosilylation reactions. And then, α-naphthalenyl was connected to the core by using Suzuki coupling reaction. This gave a new carbosilane dendrimer with a 4-(naphthalen-1-yl)phenyl core. All the products were characterized by IR, 1HNMR, 13CNMR, 29SiNMR, and MS. The study shows that Suzuki Coupling reaction is an effective and powerful core- functionalization method and a satisfactory result can be achieved through prolonging the reaction time.
Preparation and characterization of inclusion complex of carbosilane dendrimers and cyclodextrins
Zhu, Lin,Liu, Huashi,Guan, Ruifang,Zhou, Chuanjian
, p. 8775 - 8779 (2013/11/06)
In this paper, 1st-4th generation of carbosilane dendrimers [G 1(PhBr)-G4(PhBr)] were synthesized with bromophenyl group as a core molecule. Then, the inclusion reaction of α-, β-, γ-cyclodextrin and four generations of carbosilane d
