282716-03-4

Basic information

• Product Name: Benzene, 1-methoxy-4-[[(3-phenyl-2-propenyl)oxy]methyl]-
• CAS NO: 282716-03-4
• Molecular Formula: C17H18O2
• Molecular Weight: 254.329
• Mol File: 282716-03-4.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[[(3-phenyl-2-propenyl)oxy]methyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[[(3-phenyl-2-propenyl)oxy]methyl]-(282716-03-4)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[[(3-phenyl-2-propenyl)oxy]methyl]-(282716-03-4)

Safety Data

• Hazardous Substances Data: 282716-03-4(Hazardous Substances Data)

Upstream product

• 105-13-5 4-Methoxybenzyl alcohol 
• 124517-47-1 cinnamyl tert-butyl carbonate 
• 104-54-1 3-Phenylpropenol 
• 824-94-2 p-methoxybenzyl chloride 
• 89238-99-3 O-(4-methoxybenzyl)-trichloroacetimidate 
• 673-32-5 1-Phenylprop-1-yne 

Downstream Products

• 104-54-1 3-Phenylpropenol 
• 104-55-2 3-phenyl-propenal 

Relevant articles and documents

Sustainable, mild and efficient p-methoxybenzyl ether deprotections utilizing catalytic DDQ

A procedure for the selective deprotection of p-methoxybenzyl ethers using catalytic amounts of DDQ and of sodium nitrite, with oxygen as the terminal oxidant, is reported.

A convenient approach for the deprotection and scavenging of the PMB group using POCl3

A convenient and high yielding approach for the deprotection and scavenging of the p-methoxybenzyl (PMB) group in PMB ethers and PMB esters was developed using POCl3 as the reagent. 4-Methoxybenzyl chloride, a starting material used for the preparation of PMB ethers and esters was regenerated in the deprotection step. This mild and selective procedure tolerates several acid sensitive functional groups. The Royal Society of Chemistry 2013.

Mild, selective deprotection of PMB ethers with triflic acid/1,3-dimethoxybenzene

An efficient method for the cleavage of the p-methoxybenzyl protecting group of several alcohols in the presence of 0.5 equiv of trifluoromethanesulfonic acid and 1,3-dimethoxybenzene in dichloromethane at room temperature is described.