2830-12-8Relevant academic research and scientific papers
CROSS-LINKING AGENT FOR CROSS-LINKABLE ELASTOMERS AND APPLICATION THEREOF
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Paragraph 0043, (2013/03/26)
The object of the present invention to provide a cross-linking agent for a cross-linkable elastomer which is excellent in the heat resistance and rapid in the cross-linking rate in comparison with triallyl isocyanurate (TAIC). The present invention relates to a cross-linking agent for a cross-linkable elastomer comprising a triazine derivative represented by the general formula (I) or prepolymer thereof. (In the formula (I), at least two of X, Y and Z are each independently a diallylamino group, a mono-allyl amino group or allyl-methylamino group, and the rest is a hydrogen atom or a hydrocarbon group which may be substituted.)
Highly pyramidalised heteroaromatic nitrogens in discrete multinuclear silver(i) complexes assembled from bis- and tris-(diallylamino)azines
Kelemu, Solomon W.,Steel, Peter J.
, p. 9072 - 9079 (2013/11/19)
2,4-Bis(diallylamino)-6-chloro-1,3,5-triazine reacts with silver(i) perchlorate and triflate to form discrete M4L2 assemblies in which the ligand uses all seven available (allyl and triazine) donors. 2,4,6-Tris(diallylamino)pyrimidine forms a discrete M2L complex with silver triflate, in which the ligand is hypodentate. 2,4,6-Tris(diallylamino)-1, 3,5-triazine forms a 1-D coordination polymer with silver perchlorate using seven donor groups, but employs all nine donors to form a discrete M 3L complex with silver triflate. In all these structures the nitrogen donors show unusually high levels of pyramidalisation.
