28525-26-0Relevant articles and documents
The Feeble Nucleofugality of a Nitronate Leaving Group and its Enhancement by Ring Strain
Piras, Pier Paolo,Thomas, Patsy J.,Stirling, Charles J. M.
, p. 658 - 659 (1982)
The rank of a nitronate ion in activated alkene-forming elimination is low (+2.6); incorporation of the leaving group in a cyclopropane accelerates elimination so much that the E1cB)R-(E1cB)l borderline is traversed but the retro-Thorpe-Ingold effect nevertheless operates.
2-Bromoethyl glycosides for synthesis of glycoconjugates on solid support
Ellervik, Ulf,Jacobsson, M?rten,Ohlsson, J?rgen
, p. 2421 - 2429 (2007/10/03)
2-Bromoethyl glycosides can easily and in high yields be transformed into sulfones by treatment with a suitable thiol followed by oxidation with mCPBA. The observation that the so formed sulfones were cleaved by treatment with NaOMe/MeOH was used to desig
β-Eliminations in Isonitriles
Jones, Beverly A.,Varma, Manju,Stirling, Charles J. M.
, p. 3153 - 3154 (2007/10/02)
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