Journal of the Chemical Society. Chemical communications p. 658 - 659 (1982)
Update date:2022-08-28
Topics:
Piras, Pier Paolo
Thomas, Patsy J.
Stirling, Charles J. M.
The rank of a nitronate ion in activated alkene-forming elimination is low (+2.6); incorporation of the leaving group in a cyclopropane accelerates elimination so much that the E1cB)R-(E1cB)l borderline is traversed but the retro-Thorpe-Ingold effect nevertheless operates.
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