phenyl selenosulfide

Base Information

• Chemical Name: phenyl selenosulfide
• CAS No.: 28622-58-4
• Molecular Formula: C₁₂H₁₀SSe
• Molecular Weight: 265.237
• Mol file: 28622-58-4.mol

Synonyms:phenyl selenosulfide

Chemical Property of phenyl selenosulfide

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of phenyl selenosulfide

There total 13 articles about phenyl selenosulfide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 76.0%

diphenyl diselenide (1666-13-3) + benzenesulfenyl chloride (931-59-9) → phenyl selenosulfide (28622-58-4)

Guidance literature:

diphenyl diselenide; With samarium diiodide; In tetrahydrofuran; at 20 ℃; for 4h;

benzenesulfenyl chloride; In tetrahydrofuran; at 20 ℃; for 4h;

Reference yield: 69.0%

(py)8Th4(μ3-Se)4(μ2-SePh)4(η-SePh)4*6.25py + diphenyldisulfane (882-33-7) → diphenyl sulfide (139-66-2) + diphenylselenide (1132-39-4) + diphenyl diselenide (1666-13-3) + phenyl selenosulfide (28622-58-4) + (pyridine)4thorium(IV)(SPh)4

Guidance literature:

With pyridine; at 90 ℃; for 96h; Inert atmosphere;

DOI:10.1021/acs.inorgchem.8b00836

Reference yield:

benzophenone tosylhydrazone (4545-20-4) + diphenyldisulfane (882-33-7) → benzophenone (119-61-9) + phenyl toluene-4-thiosulfonate (3541-14-8) + phenyl selenosulfide (28622-58-4) + p-tolyl benzeneselenosulfonate (68819-94-3)

Guidance literature:

With benzeneseleninic anhydride; In chloroform; at 25 ℃; for 1h; Further byproducts given;

DOI:10.1016/S0040-4020(01)96097-1

upstream raw materials:

phenyl selenocyanate

thiophenol

Phenylselenyl bromide

benzophenone tosylhydrazone

Downstream raw materials:

(Z)-3-(phenylseleno)-2-(phenylthio)prop-2-en-1-ol

(Z)-4-(phenylseleno)-3-(phenylthio)-2-methylbut-3-en-2-ol

(Z)-1-(phenylseleno)-2-(phenylthio)-3-methoxyprop-1-ene

(Z)-1-(phenylseleno)-2-(phenylthio)-3-phenoxyprop-1-ene