28637-46-9

Upstream product

• 7440-31-5 tin 
• 882-33-7 diphenyldisulfane 
• 7646-78-8 tin(IV) chloride 
• 108-98-5 thiophenol 
• 595-90-4 tetraphenyltin(IV) 
• 16528-57-7 tin(II) benzenethiolate 

Downstream Products

• 186509-35-3 Sn(thiophenolate)2(pyridine-2-selenolate)2 
• 129690-31-9 tin(pyridine-2-thiolate)3(phenylthiolate) 
• 129674-80-2 tin(pyridine-2-thiolate)(phenylthiolate)3 
• 99899-12-4 Sn(SC₆H₅)2(SeC₆H₅)2 
• 99899-11-3 Sn(SC₆H₅)3(SeC₆H₅) 
• 99899-13-5 Sn(SC₆H₅)(SeC₆H₅)3 

Relevant academic research and scientific papers

Reactions of Some Main Group Metals with Diphenyl Disulphide and Diphenyl Diselenide

Indium reacts with both Ph2S2 and Ph2Se2 in refluxing toluene to give the compounds In(EPh)3 (E = S or Se) in high yield.Under similar conditions tin gives Sn(EPh)4.Thallium reacts with Ph2Se2 to form Tl(SePh), but does not react with Ph2S2.Neither zinc nor gallium reacts with Ph2S2 or Ph2Se2.With mixtures of Ph2E2 and I2, indium yields the previously unreported InI(EPh)2 compounds.The reactions of In(SePh)3 are those of a typical indium(III) Lewis acid.Possible factors affecting the reactions of metals with Ph2S2 or Ph2Se2 are briefly discussed.