286967-48-4

Upstream product

• 89398-25-4 (S)-2-phenylethyl 4-methylbenzenesulfonate 
• 1044771-26-7 4(S)-2-methoxy-2-methyl-4-phenyl-1,3-dioxolane 
• 103590-74-5 (R)-(+)-2-chloro-2-phenethylacetic acid 
• 25779-13-9 (S)-1-phenyl-1,2-ethanediol 
• 21210-43-5 (S)-Methyl mandelate 
• 10606-75-4 (S)-2-Phenyl<2-²H₁>ethanol 
• 17199-29-0 (S)-Mandelic acid 

Downstream Products

• 286967-47-3 1-trimethylsilyloxy-3(S)-[2-deutero-2(S)-phenethyl]-5(R)-methyl-1-cyclohexene 
• 883236-68-8 N-p-toluenesulfonyl-2-(2-phenylethyl)-3-pyrroline 
• 1414335-87-7 C₂₆H₂₃⁽²⁾HP⁽¹⁺⁾*Br^(1-) 

Relevant academic research and scientific papers

Reconciling the stereochemical course of nucleopalladation with the development of enantioselective wacker-type cyclizations

A stereochemical substrate probe was used to assess the factors that affect the stereochemical course of nucleopalladation in the context of an enantioselective Wacker-type reaction. The enantioselectivity correlates directly with the nucleopalladation pathway, and both the neutral-donor and anionic ligands on palladium are capable of controlling selectivity for cis- or trans-nucleopalladation (see scheme; TFA=trifluoroacetate). Copyright