382593-86-4

Upstream product

• 1125-88-8 benzaldehyde dimethyl acetal 
• 99096-92-1 (2R,3R)-5-hexen-1,2,3-triol 
• 288069-39-6 (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one 
• 288069-37-4 (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine 

Downstream Products

• 288069-39-6 (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one 

Relevant academic research and scientific papers

Synthesis of Luffarin L and 16- epi -Luffarin L Using a Temporary Silicon-Tethered Ring-Closing Metathesis Reaction

The first synthesis of luffarin L (1) and 16-epi-luffarin L (2) by a silicon-tethered ring closing metathesis as a key step has been achieved. The stereochemistry and absolute configuration of the natural sesterterpenolide luffarin L (1) and a new route f

Synthesis of all diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses from 2-phenyl-1,3-dioxan-5-one hydrate

All diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses were synthesized from 2-phenyl-1,3-dioxan-5-one hydrate (1), by alkylation via the RAMP-hydrazone (2). Some of the diastereomers were synthesized in the racemic form via the dimethylhydrazone (28). The 2-deoxypentoses were synthesized by alkylation with allyl bromide, followed by stereoselective reduction, ozonolysis, and deprotection. The 2,6-dideoxypentoses were synthesized by dialkylation with allyl bromide and methyl iodide.