288069-37-4

Basic information

• Product Name: (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine
• Synonyms: (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine
• CAS NO: 288069-37-4
• Molecular Weight: 330.427
• Mol File: 288069-37-4.mol

Chemical Properties

• CAS DataBase Reference: (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine(CAS DataBase Reference)
• NIST Chemistry Reference: (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine(288069-37-4)
• EPA Substance Registry System: (E)-(2R,2'S,4'R)-(-)-1-(4-allyl-2-phenyl-1,3-dioxan-5-ylideneamino)-2-(methoxymethyl)pyrrolidine(288069-37-4)

Safety Data

• Hazardous Substances Data: 288069-37-4(Hazardous Substances Data)

Upstream product

• 106-95-6 allyl bromide 

Downstream Products

• 382593-87-5 (2S,4R,5S,6R)-(-)-4-allyl-6-methyl-2-phenyl-1,3-dioxan-5-ol 
• 382593-80-8 (2S,4R,6R)-(+)-4-allyl-6-methyl-2-phenyl-1,3-dioxan-5-one 
• 382593-86-4 (2S,4R,5R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-ol 
• 288069-39-6 (2S,4R)-(+)-4-allyl-2-phenyl-1,3-dioxan-5-one 

Relevant articles and documents

Synthesis of all diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses from 2-phenyl-1,3-dioxan-5-one hydrate

All diastereomers of the 2-deoxypentoses and the 2,6-dideoxyhexoses were synthesized from 2-phenyl-1,3-dioxan-5-one hydrate (1), by alkylation via the RAMP-hydrazone (2). Some of the diastereomers were synthesized in the racemic form via the dimethylhydrazone (28). The 2-deoxypentoses were synthesized by alkylation with allyl bromide, followed by stereoselective reduction, ozonolysis, and deprotection. The 2,6-dideoxypentoses were synthesized by dialkylation with allyl bromide and methyl iodide.