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2883-99-0

3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium, also known as 3-acetyl-1-[2-(indol-3-yl)ethyl]pyridinium, is a complex organic compound with the molecular formula C16H14N2O. It is a derivative of pyridinium, featuring an acetyl group (CH3CO-) at the 3-position and an indole-containing ethyl group at the 1-position. The indole moiety is attached to the pyridinium ring through an ethyl linker, and the indole itself has a nitrogen atom in the 1H position, which is part of the aromatic system. 3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium is of interest in the field of organic chemistry and may have potential applications in the synthesis of pharmaceuticals or other chemical products due to its unique structure and reactivity.

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  • 2883-99-0 Structure

  • Basic information

    1. Product Name: 3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium
    2. Synonyms:
    3. CAS NO:2883-99-0
    4. Molecular Formula: C17H17N2O
    5. Molecular Weight: 265.3291
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 2883-99-0.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: N/A
    4. Appearance: N/A
    5. Density: N/A
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium(CAS DataBase Reference)
    10. NIST Chemistry Reference: 3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium(2883-99-0)
    11. EPA Substance Registry System: 3-acetyl-1-[2-(1H-indol-3-yl)ethyl]pyridinium(2883-99-0)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 2883-99-0(Hazardous Substances Data)

2883-99-0 Usage

Check Digit Verification of cas no

The CAS Registry Mumber 2883-99-0 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 2,8,8 and 3 respectively; the second part has 2 digits, 9 and 9 respectively.
Calculate Digit Verification of CAS Registry Number 2883-99:
(6*2)+(5*8)+(4*8)+(3*3)+(2*9)+(1*9)=120
120 % 10 = 0
So 2883-99-0 is a valid CAS Registry Number.

2883-99-0SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 16, 2017

Revision Date: Aug 16, 2017

1.Identification

1.1 GHS Product identifier

Product name 1-[1-[2-(1H-indol-3-yl)ethyl]pyridin-1-ium-3-yl]ethanone,bromide

1.2 Other means of identification

Product number -
Other names -

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

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More Details:2883-99-0 SDS

2883-99-0Relevant articles and documents

Construction of Chiral Tetrahydro-β-Carbolines: Asymmetric Pictet–Spengler Reaction of Indolyl Dihydropyridines

Wang, Shou-Guo,Xia, Zi-Lei,Xu, Ren-Qi,Liu, Xi-Jia,Zheng, Chao,You, Shu-Li

supporting information, p. 7440 - 7443 (2017/06/13)

A highly efficient synthesis of the enantioenriched tetrahydro-β-carbolines was developed by using a chiral phosphoric acid catalyzed Pictet–Spengler reaction of indolyl dihydropyridines. The reaction proceeds under mild reaction conditions to afford the desired chiral tetrahydro-β-carbolines in good to excellent yields (up to 96 %) and high enantioselectivities (up to 99 % ee). With this method, a formal synthesis of tangutorine and a total synthesis of deplancheine were achieved in a highly efficient manner.

GENERAL METHODS OF SYNTHESIS OF INDOLE ALKALOIDS - 14. SHORT ROUTES OF CONSTRUCTION OF YOHIMBOID AND AJMALICINOID ALKALOID SYSTEMS AND THEIR 13C NUCLEAR MAGNETIC RESONANCE SPECTRAL ANALYSIS.

Wenkert,Chang,Chawla,Cochran,Hagaman,King,orito

, p. 3645 - 3661 (2007/10/04)

Conceptually new schemes of synthesis of indole alkaloids are introduced. The yohimboid ring system is constructed by the sequential treatment of 1-tryptophyl-3-( beta -ketobutyl)pyridinium bromide with base and acid. Hydrogenation of the product yields d,l-pseudoyohimbone. The ajmalicinoid ring system is formed by the exposure of 1-tryptophyl-3-acetylpyridinium bromide to sodio dimethyl malonate and then to acid, followed by hydrogenation. Subsequent reduction and dehydration of the products lead to the racemates of the alkaloids tetrahydroalstonine and akuammigine as well as isomers of ajmalicine. Shifts of specific carbons are found to be of stereochemically diagnostic value.

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