288313-99-5

Basic information

• Product Name: (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE
• Synonyms: (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE
• CAS NO: 288313-99-5
• Molecular Formula: C₁₁H₁₃N₇
• Molecular Weight: 243.27
• Mol File: 288313-99-5.mol
• Article Data: 6

Chemical Properties

• Appearance: /
• CAS DataBase Reference: (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE(288313-99-5)
• EPA Substance Registry System: (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE(288313-99-5)

Safety Data

• Hazardous Substances Data: 288313-99-5(Hazardous Substances Data)

Usage

General Description

(3S,4S)-3,4-Diazido-1-(phenylmethyl)pyrrolidine is an organic compound consisting of a pyrrolidine ring with two azido groups and a phenylmethyl group attached. It is a chiral compound with the (3S,4S) configuration, meaning that the substituents are oriented in a specific spatial arrangement. (3S,4S)-3,4-DIAZIDO-1-(PHENYLMETHYL)PYRROLIDINE has potential applications in chemical synthesis and as a building block for the development of new materials or pharmaceuticals. The azido groups can participate in a variety of chemical reactions, such as azide-alkyne cycloaddition, which can be useful in creating new molecular structures and functional materials. However, care must be taken when handling this compound due to its potential explosive properties. Overall, (3S,4S)-3,4-Diazido-1-(phenylmethyl)pyrrolidine is a versatile and potentially valuable compound with interesting chemical properties.

Upstream product

• 163439-82-5 (3R,4R)-1-benzyl-3,4-pyrrolidinediol 
• 75172-31-5 (3R,4R)-1-benzyl-3,4-dihydroxypyrrolidine-2,5-dione 
• 100-46-9 benzylamine 
• 90365-74-5 (3S,4S)-(+)-1-benzyl-3,4-pyrrolidinediol 
• 187032-53-7 (3S,4S)-1-N-benzyl-3,4-dihydroxypyrrolidine-2,6-dione 
• 380357-38-0 (3R,4R)-1-Benzyl-3,4-bis(methylsulfonyloxy)pyrrolidin 
• 104351-40-8 (3S,4S)-1-benzyl-3,4-pyrrolidinediyl bis(methanesulfonate) 

Downstream Products

• 1000303-14-9 (3S,4S)-4-azido-1-benzylpyrrolidin-3-ylamine 
• 1293389-12-4 C₁₅H₁₉N₅O 
• 1293389-13-5 C₁₆H₂₁N₅O 
• 1000303-34-3 ((3'S,4'S)-1'-benzyl-2-oxo-[1,3']bipyrrolidinyl-4'-yl)carbamic acid tert-butyl ester 
• 1000303-31-0 [(3S,4S)-1-benzyl-4-(2-oxopiperidin-1-yl)pyrrolidin-3-yl]carbamic acid tert-butyl ester 
• 1000303-28-5 ((3S,4S)-4-azido-1-benzylpyrrolidin-3-yl)carbamic acid tert-butyl ester 
• 266692-94-8 N-benzyl-3,4-di(Boc-amino)pyrrolidine 
• 288314-03-4 (3S,4S)-3,4-Bis-[((1R,2R)-2-{2-[4-(2-{ethyl-[4-(4-nitro-phenylazo)-phenyl]-amino}-ethoxy)-phenyl]-ethylcarbamoyl}-cyclohexanecarbonyl)-amino]-pyrrolidine-1-carboxylic acid 2-trimethylsilanyl-ethyl ester 
• 193352-75-9 (3S,4S)-1-benzyl-pyrrolidine-3,4-diamine 

Relevant articles and documents

Urea vs. carbamate groups: a comparative study in a chiral C2 symmetric organogelator

The effect of the replacement of molecular moieties (carbamates vs. urea) that drive self-assembly for two organogelators with an identical C2 symmetric molecular structure is described. The main properties of the gels obtained from the urea-ba

Substituted 3-Amino-Pyrrolidino-4-Lactams

The invention provides compounds of formula (1), and the pharmaceutically acceptable salt thereof, wherein R1, n and R2 are as described herein; compositions thereof; and uses thereof.

Combinatorial chemistry for ligand development in catalysis: Synthesis and catalysis screening of peptidosulfonamide tweezers on the solid phase

On the basis of a pyrrolidine tweezer 1, a library of peptidosulfonamide tweezers (15a-e, 16a-e was synthesized on the solid phase. This library was screened in a simultaneous substrate screening procedure for the ability to enantioselectively catalyze the Ti(O-i-Pr)4-mediated addition of diethylzinc to aldehydes. One of the best solid-phase tweezer catalyst (i.e., 16d, giving an ee of 32% in solid-phase catalysis) was resynthesized in solution (compounds 20 and 21). The now homogeneous solution-phase catalysis showed even better enantioselectivity (i.e., up to 66%).