28854-39-9

Basic information

• Product Name: Isobornyl 2-methyl-2-propenoate
• Synonyms: [(1R,4R,6R)-1,7,7-Trimethyl-6-bicyclo[2.2.1]heptanyl] 2-methylprop-2-enoate;Isobornyl 2-methyl-2-propenoate
• CAS NO: 28854-39-9
• Molecular Formula: C14H22O2
• Molecular Weight: 222.32
• EINECS: 231-403-1
• Mol File: 28854-39-9.mol
• Article Data: 10

Chemical Properties

• Boiling Point: 160.5 °C at 760 mmHg
• Flash Point: 74.2 °C
• Appearance: /
• CAS DataBase Reference: Isobornyl 2-methyl-2-propenoate(CAS DataBase Reference)
• NIST Chemistry Reference: Isobornyl 2-methyl-2-propenoate(28854-39-9)
• EPA Substance Registry System: Isobornyl 2-methyl-2-propenoate(28854-39-9)

Safety Data

• Hazardous Substances Data: 28854-39-9(Hazardous Substances Data)

Usage

General Description

Isobornyl 2-methyl-2-propenoate, also known as isobornyl methacrylate, is an organic compound with the chemical formula C14H22O2. It is a clear, colorless liquid with a faint odor and is commonly used as a monomer in the production of polymers and resins. Isobornyl 2-methyl-2-propenoate has a wide range of applications, including in the manufacturing of adhesives, coatings, and other industrial products. It is known for its excellent adhesion, weatherability, and chemical resistance, making it a valuable ingredient in various formulations for a variety of industries. Additionally, it is considered to have low toxicity and is generally safe for use in the production of consumer goods.

InChI:InChI=1/C14H22O2/c1-9(2)12(15)16-11-8-10-6-7-14(11,5)13(10,3)4/h10-11H,1,6-8H2,2-5H3/t10-,11-,14+/m1/s1

Upstream product

• 79-41-4 poly(methacrylic acid) 
• 5794-04-7 camphene 
• 464-43-7 borneol 
• 80-62-6 methacrylic acid methyl ester 
• 71424-71-0 iso-Bornyl acetate 
• 2226-96-2 tempol 
• 150-76-5 4-methoxy-phenol 
• 464-45-9 endo-borneol 
• 285128-05-4 di-(-)-bornyl 1,1,3,3-tetramethyl-1,3-acetonedicarboxylate 
• 760-93-0 methacryloyl anhydride 
• 24393-70-2 isoborneol 

Relevant articles and documents

Preparation method of bio-derived isobornyl (meth) acrylate

The invention belongs to the technical field of photocatalytic organic synthesis, and discloses a preparation method of bio-derived isobornyl (meth) acrylate. The method comprises the following steps:adding camphene, (methyl) acrylic acid, a polymerization inhibitor and a catalyst into a transparent reactor, uniformly mixing, placing under UV light irradiation, carrying out a stirring reaction, and carrying out reduced pressure rotary evaporation after the reaction is finished to obtain isobornyl acrylate and isobornyl methacrylate. According to the method, isobornyl (meth) acrylate is prepared by adopting a photocatalysis method, wherein the reaction conditions are mild, the reaction time is short, side reactions and byproducts are avoided, the conditions of high temperature, high pressure and the like are not needed, the separation and purification are simple and easy to operate, and the isobornyl (meth) acrylate can be obtained. According to the invention, isobornyl (meth) acrylateis prepared from a natural renewable resource camphene, so that a new application direction is opened up for the natural renewable resource vegetable oil, the economic value of the vegetable oil is improved, and the method has a good popularization effect on the development of agriculture and forestry economy.

Acrylate monomer preparation using alkali metal alkoxides as ester interchange catalysts

The present invention relates to a process to prepare alkyl (meth)acrylate esters from corresponding alkyl/methacrylate esters using an alkali metal alkoxide as an ester interchange catalyst to produce an alkyl (meth)acrylate ester monomer product C The present invention further relates to the use of bromide and iodide salts as free radical polymerization inhibitors. The present invention further relates to the use of a noninterfering alcohol or polyol that prevents anionic polymerization reactions of reactant ester B and/or alkyl (meth)acrylate product C. The present invention further relates to a process for inhibiting polymerization of (meth)acrylates being synthesized in a transesterification or ester-ester interchange reaction system

Engineering reactions in crystalline solids: Radical pairs in crystals of dialkyl 1,3-acetonedicarboxylates

(Equation presented) Crystalline dialkyl 1,3-acetonedicarboxylates give dialkyl succinates in high chemical yields by combination of α-carbonyl radical pairs produced by photochemical decarbonylation. It is proposed that the solid-state reaction depends on the exothermicity of two consecutive bond cleavage processes. It is also suggested that the efficiency of radical formation in the solid state is determined by the effect of substituents on bond dissociation energies and radical-stabilization abilities.