28860-18-6Relevant articles and documents
Time-Resolved EPR Revealed the Formation, Structure, and Reactivity of N -Centered Radicals in an Electrochemical C(sp3)-H Arylation Reaction
Alhumade, Hesham,Gao, Renfei,Huang, Cunlong,Lei, Aiwen,Liu, Yichang,Liu, Zhao,Qi, Xiaotian,Shi, Biyin,Wang, Shengchun
supporting information, p. 20863 - 20872 (2021/12/14)
Electrochemical synthesis has been rapidly developed over the past few years, while a vast majority of the reactions proceed through a radical pathway. Understanding the properties of radical intermediates is crucial in the mechanistic study of electroche
Evidence for an Isocyanate Formation in the Alkaline Hydrolysis of N1-Alkyl Derivatives of Chlorpropamide, Inhibitors of Aldehyde Dehydrogenase
Bergon, M.,Vigroux, A.,Tisnes, P.
, p. 946 - 947 (2007/10/02)
Trapping of a propyl isocyanate intermediate and entropies of activation data are consistent with an elimination-addition mechanism AxhDH + DN (E1cB) for the hydrolysis of 1-alkyl-1--3-n-propylurea, the N1-alkyl derivatives of chlorpropamide, inhibitors of aldehyde dehydrogenase.