289619-06-3

Basic information

• Product Name: (4S)-3-[(2R)-2-allyloxypent-4-enoyl]-4-benzyloxazolidin-2-one
• Synonyms: (4S)-3-[(2R)-2-allyloxypent-4-enoyl]-4-benzyloxazolidin-2-one
• CAS NO: 289619-06-3
• Molecular Weight: 315.369
• Mol File: 289619-06-3.mol

Chemical Properties

• CAS DataBase Reference: (4S)-3-[(2R)-2-allyloxypent-4-enoyl]-4-benzyloxazolidin-2-one(CAS DataBase Reference)
• NIST Chemistry Reference: (4S)-3-[(2R)-2-allyloxypent-4-enoyl]-4-benzyloxazolidin-2-one(289619-06-3)
• EPA Substance Registry System: (4S)-3-[(2R)-2-allyloxypent-4-enoyl]-4-benzyloxazolidin-2-one(289619-06-3)

Safety Data

• Hazardous Substances Data: 289619-06-3(Hazardous Substances Data)

Upstream product

• 556-56-9 allyl iodid 
• 197721-28-1 (4S)-3-(2-allyloxyethanoyl)-4-benzyloxazolidin-2-one 
• 22577-14-6 2-(allyloxy)acetic acid 
• 90719-32-7 (S)-4-Benzyl-2-oxazolidinone 
• 318488-46-9 α-allyloxyacetyl pivaloyl anhydride 

Downstream Products

• 445027-86-1 (4S)-3-[(R)-3,6-dihydro-2H-pyran-2-ylmethanoyl]-4-benzyloxazolidin-2-one 

Relevant articles and documents

Synthesis of enantiomerically pure divinyl- and diallylcarbinols

Acylated oxazolidinones and bornane sultams can be cleaved to divinyl- and diallylcarbinols by treatment with vinyl- or allylmetal compounds. For the preparation of divinylcarbinols, acylated bornane sultams are the starting materials of choice, while for the preparation of diallylcarbinols acylated oxazolidinones and bornane sultams work equally well.

Diastereoselective alkylations of oxazolidinone glycolates: A useful extension of the Evans asymmetric alkylation

matrix presented The diastereoselective alkylation of glycolate oxazolidinones has been demonstrated as a method for the enantioselective preparation of α-alkoxy carboxylic acid derivatives and selectively protected 1,2-diols. Various protecting groups on